Abstract
The crystal and molecular structure of β-(N-benzothiazoline-2-one)propionic acid and its ethylenediammonium salt is studied. In the latter structure, amine groups of ethylenediamine are involved in the deprotonation of two molecules of β-(N-benzothiazoline-2-one)propionic acid. The geometry of the molecules and weak intermolecular hydrogen and dative bonds in the crystals are analyzed. The asymmetric unit of the unit cell in both structures contains two molecules of β-(N-benzothiazoline-2-one)propionic acid.
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J. M. Ashurov, N. S. Mukhammedov, B. Tashkhodzhaev, and B. T. Ibragimov, J. Struct. Chem, 2015, 56(6), 1148–1153.
D. A. Dushamov, U. Kh. Yakubov, R. G. Aflyatunova, F. B. Zhonkhozhaeva, and N. A. Aliev, Uz. Chem. J., 2003, (6),7.
Lo Chen-Pen. US Patent US3050526.
N. N. Melnikov and E. I. Andreeva, Khimiya v Selskom Khoziaistve, 1973, (3),29.
M. Mellor and C. R. Steele. England Patent EP0245991 A2.
L. Nusslein and F. Arndt. US Patent US4183739 A.
N. N. Melnikov. Pesticide Chemistry and Technology [in Russian]. Khimiya, Moscow, 1974.
Yu. A. Baskakov, Zh. Ross. Khim. ob-va im. D. I. Mendeleeva, 1984, 29(1),22.
J. J. D'Amico. US Patent US 3993468.
J. J. D'Amico and J. T. Marvel. US Patent US 4283220.
M. J. Klingensmith and N. Y. Hamilton. Am. J. Bot., 1961, 48,40.
I. P. Tsukervanik, Uzb. Khim. Zh., 1961, 1,44.
G. M. Sheldrick. Program for Empirical Absorption Correction of Area Detector Data, Goettingen: University of Goettingen, 1996.
G. M. Sheldrick. Acta Crystallogr., 2008, A64,112.
A. Aydin, T. Onkol, C. Arici, M. Akkurt, M. F. Sahin, and D. Ulku. Acta Crystallogr., Sect. E: Struct. Rep. Online, 2003, 59, o616.
A. Aydin, M. Akkurt, T. Onkol, and O. Buyukgungor. Z. Kristallogr., New Cryst. Struct., 2010, 225, 511.
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Original Russian Text © 2018 J. M. Ashurov, L. Yu. Izotova, B. Tashkhodzhaev, M.I. Olimova, B.T. Ibragimov.
Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 3, pp. 707–711, March-April, 2018.
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Ashurov, J.M., Izotova, L.Y., Tashkhodzhaev, B. et al. Crystal and Molecular Structure of β-(N-Benzothiazoline-2-One)Propionic Acid and Its Ethylenediammonium Salt. J Struct Chem 59, 684–688 (2018). https://doi.org/10.1134/S0022476618030277
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DOI: https://doi.org/10.1134/S0022476618030277