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Crystal Structure and Properties of Two Samarium Β-Diketonates

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Abstract

Samarium(III) tris-dipivaloylmethanate [Sm(dpm)3]2 (I) and sodium samarium(III) tetrakishexafluoroacetylacetonate [NaSm(hfa)4]n (II) are obtained. The crystal structures of I at 150(2) K (space group P21/n, a = 12.279(1) Å, b = 27.726(3) Å, с = 21.884(2) Å, β = 105.317(3)°, V = 7186.0(11) Å3, Z = 4) and II at 150(2) K (space group C2/c, a = 21.693(2) Å, b = 12.2068(7) Å, с = 14.402(1) Å, β = 124.731(3)°, V = 3134.2(4) Å3, Z = 4) are determined. The structure of the complex I is similar to that of the previously known dimeric [Ln(dpm)3]2 (Ln = La, Pr, Nd, Eu, Gd, Tb) complexes; and the structure of the complex II is similar to that of the known [NaLn(hfa)4]n (Ln = Y, Eu, Er) complexes. It is shown by thermogravimetry that the volatility of REE tris-dipivaloylmethanates increases from Lu to La, the volatility of REE sodium tetrakis-hexafluoroacetylacetonates increases from La to Lu.

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References

  1. V. A. Mode and G. S. Smith. J. Inorg. Nucl. Chem., 1969, 31, 1857–1859.

    Article  CAS  Google Scholar 

  2. C. S. Erasmus and J. C. A. Boeyens. Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1970, 26, 1843–1854.

    Article  CAS  Google Scholar 

  3. J. P. R. de Villiers and J. C. A. Boeyens. Acta Crystallogr., Sect. B, 1971, 27, 2335–2340.

    Article  Google Scholar 

  4. Lu Yuikhan, S. A. Mosyagina, P. A. Stabnikov, et al., J. Struct. Chem., 2017, 58(4), 843–846.

    Article  Google Scholar 

  5. P. A. Stabnikov, S. A. Mosyagina, K. V. Zherikova, et al., J. Struct. Chem., 2017, 58(8), 1693–1696.

    Article  CAS  Google Scholar 

  6. S. Shibata, K. Iijima, T. Inuzuka, et al. J. Mol. Struct., 1986, 144, 351–357.

    Article  CAS  Google Scholar 

  7. E. Giera. J. Chem. Thermodyn., 2000, 32, 821–833.

    Article  CAS  Google Scholar 

  8. V. V. Rybkin, N. V. Tverdova, G. V. Girichev, et al. J. Mol. Struct., 2011, 1006, 173–179.

    Article  CAS  Google Scholar 

  9. K. J. Eisentraut and R. E. Sievers. J. Am. Chem. Soc., 1965, 87, 5254–5256.

    Article  CAS  Google Scholar 

  10. Bruker AXS Inc., APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11), Bruker Advanced Xray Solutions, Madison, Wisconsin, USA, 2004.

  11. M. C. Burla, R. Caliandro, B. Carrozzini, et al. Appl. Crystallogr., 2015, 48, 306–309.

    Article  CAS  Google Scholar 

  12. G. M. Sheldrick. SHELX97 Release 97–2, University of Gottingen, Germany, 1998.

    Google Scholar 

  13. G. M. Sheldrick. Acta Crystallogr., 2008, A64, 112–122.

    Article  CAS  Google Scholar 

  14. P. A. Stabnikov, I. V. Korolkov, N. V. Pervukhina, O. V. Antonova, et al., Russ. J. Gen. Chem., 2015, 85, 144–153.

    Article  CAS  Google Scholar 

  15. I. Baxter, S. R. Drake, M. B. Hursthouse, et al. Inorg. Chem., 1995, 34, 1384–1394.

    Article  CAS  Google Scholar 

  16. P. A. Stabnikov, G. I. Zharkova, A. I. Smolentsev, N. V. Pervukhina, and S. V. Krisyuk, J. Struct. Chem., 2011, 52(3), 560–567.

    Article  CAS  Google Scholar 

  17. M. C. Barry, Wei Zheng, He Tianyu, et al. J. Am. Chem. Soc., 2016, 138(28), 8883–8887.

    Article  CAS  PubMed  Google Scholar 

  18. A. Monguzzi, A. Milani, A. Mech, et al. Synth. Met., 2012, 161, 2693–2699.

    Article  CAS  Google Scholar 

  19. F. H. Allen, O. Kennard, and D. G. Watson. J. Chem. Soc., Perkin Trans., 1987, S1–S19.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. Urkasym kyzy, I. V. Korolkov, N. V. Pervukhina, V. V. Krisyuk & P. A. Stabnikov

  2. Novosibirsk State University, Novosibirsk, Russia

    Huang Shen, S. A. Mosyagina, I. V. Korolkov & N. V. Pervukhina

Authors
  1. S. Urkasym kyzy
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  2. Huang Shen
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  3. S. A. Mosyagina
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  4. I. V. Korolkov
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  5. N. V. Pervukhina
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  6. V. V. Krisyuk
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  7. P. A. Stabnikov
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Correspondence to S. Urkasym kyzy.

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Original Russian Text © 2018 S. Urkasym kyzy, Huang Shen, S. A. Mosyagina, I. V. Korolkov, N. V. Pervukhina, V. V. Krisyuk, P. A. Stabnikov.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 2, pp. 446–450, March–April, 2018.

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kyzy, S.U., Shen, H., Mosyagina, S.A. et al. Crystal Structure and Properties of Two Samarium Β-Diketonates. J Struct Chem 59, 433–438 (2018). https://doi.org/10.1134/S0022476618020269

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