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Crystal Structure of a 1D Silver(I) Coordination Polymer Containing Flexible bis(benzimidazole)

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Abstract

An Ag(I) coordination polymer {[Ag(L)(Htbip)]} n (H2tbip = 5-tert-butylisophthalic acid, L = 1,1-(1,4- butanediyl)bis-1H-benzimidazole) is synthesized and characterized by the elemental analysis, infrared spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. It crystallizes in the monoclinic space group P21/c, a = 18.2755(13), b = 8.8515(6), c = 18.4000(13) Å, β = 104.9200(10)°, V = 2876.1(3) Å3, Z = 4, C30H31,AgN4O4, Mr = 619.46, Dc = 1.431 g/cm3, μ = 0.742 mm−1. The structural analyses display that this compound has a 1D zigzag chain structure which is further extended into a 3D supramolecular framework through O–H⋯O hydrogen bond interactions. The complex can be stable up to 215°C.

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Authors and Affiliations

  1. College of Chemical Engineering, North China University of Science and Technology, Tangshan, Hebei Province, P. R. China

    J. W. Cui, S. C. Wang, Y. Y. Wang & G. Y. Dong

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  1. J. W. Cui
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  2. S. C. Wang
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  3. Y. Y. Wang
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  4. G. Y. Dong
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Corresponding author

Correspondence to G. Y. Dong.

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Original Russian Text © 2018 J. W. Cui, S. C. Wang, Y. Y. Wang, G. Y. Dong.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 229–232, January–February, 2018.

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Cui, J.W., Wang, S.C., Wang, Y.Y. et al. Crystal Structure of a 1D Silver(I) Coordination Polymer Containing Flexible bis(benzimidazole). J Struct Chem 59, 227–230 (2018). https://doi.org/10.1134/S0022476618010365

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  • DOI: https://doi.org/10.1134/S0022476618010365

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