Abstract
Crystalline nickel(II) decatungstate (II) [Ni(C2H6SO)5(H2O)]2[W10O32] is synthesized for the first time and characterized by chemical and thermal analyses, scanning electron microscopy, IR and Raman spectroscopy, and single crystal X-ray diffraction (XRD). By single crystal XRD the crystallographic characteristics of [Ni(C2H6SO)5(H2O)]2[W10O32] are determined (triclinic crystal system, space group P–1, a = 11.9339(7) Å, b = 12.2083(6) Å, c = 12.2083(6) Å, α = 75.235(5)°, β = 71.289(6)°, γ = 87.785(4)°, V = 1692.44(17) Å3 at T = 293(2) K, Z = 1, dx = 3.223 g/cm3) and the structure is found to be composed of isolated [Ni(C2H6SO)5(H2O)] 4+2 cation complexes and [W10O32]4– anions located in the voids between the cation complexes. By the powder XRD analysis it is shown that the crystals formed by growing from the solution do not contain impurities.
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Original Russian Text © 2018 E. Yu. Poimanova, A. O. Medved’, S. V. Radio, V. N. Baumer, G. M. Arzumanyan, N. V. Doroshkevich, E. V. Khomutova, E. E. Belousova, G. M. Rozantsev, V. T. Panyushkin.
Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 149–157, January–February, 2018.
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Poimanova, E.Y., Medved’, A.O., Radio, S.V. et al. Nickel Decatungstate [Ni(C2H6SO)5(H2O)]2[W10O32]: Synthesis from a Water-Dimethylsulfoxide Solution, Crystal Structure Determination, IR and Raman Spectroscopic Analysis, Surface Micromorphology. J Struct Chem 59, 145–153 (2018). https://doi.org/10.1134/S0022476618010225
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DOI: https://doi.org/10.1134/S0022476618010225