Skip to main content
SpringerLink
Log in

Synthesis, Structure, and Properties of the Tris(ethylendiamine)nickel(II) Dichloride Dihydrate [Ni(H2NCH2CH2NH2)3]Cl2 ⋅ 2H2O Crystals

  • CRYSTAL GROWTH
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The conditions for synthesis of [Ni(H2NCH2CH2NH2)3]Cl2 ⋅ 2H2O ([Ni(en)3]Cl2 ⋅ 2H2O) crystals from aqueous solutions have been considered. The synthesized crystals have been comprehensively studied by methods of X-ray powder and single-crystal diffraction, differential scanning calorimetry, and optical spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. V. L. Manomenova, E. B. Rudneva, and A. E. Volo-shin, Usp. Khim. 85, 585 (2016).

    Article  Google Scholar 

  2. R. Grinter, M. Harding, and S. Mason, Chem. Soc. A 667 (1970).

  3. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, Part 3 (Wiley, New York, 1988).

    Google Scholar 

  4. O. B. Zainullin, A. E. Voloshin, V. A. Komornikov, et al., Phys. Solid State 61 (12), 2415 (2019).

    Article  ADS  Google Scholar 

  5. R. Kleinberg, J. Chem. Phys. 50 (11), 4690 (1969).

    Article  ADS  Google Scholar 

  6. R. Kleinberg, J. Appl. Phys. 38 (3), 1453 (1967).

    Article  ADS  Google Scholar 

  7. H. Ptasiewicz-Bak, I. Olovsson, and G. J. McIntyre, Acta Crystallogr. B 55, 830 (1999).

    Article  Google Scholar 

  8. M. Joji, J. Phys. Soc. Jpn. 16 (8), 1574 (1961).

    Article  Google Scholar 

  9. H. M. State, Inorg. Synth. 6, 200 (1950).

    Google Scholar 

  10. Rigaku Oxford Diffraction, CrysAlisPro Software System, Version 1.171.39.46 (Rigaku Corporation, Oxford, UK, 2018).

    Google Scholar 

  11. V. Petricek, M. Dusek, and L. Palatinus, Z. Kristallogr. 229 (5), 345 (2014).

    Article  Google Scholar 

  12. L. Palatinus, Acta Crystallogr. A 60, 604 (2004).

    Article  ADS  Google Scholar 

  13. F. Hai, T. Bing, L. Ya Qin, et al., Acta Crystallogr. E Online 62, 1405 (2006).

    Google Scholar 

  14. J. E. House, Jr. and F. M. Tahir, Thermochim. Acta 118, 191 (1987).

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

This study was carried out on the equipment of the Shared Research Center of the Federal Scientific Research Center “Crystallography and Photonics” of the Russian Academy of Sciences.

Funding

This study was supported by the Ministry of Science and Higher Education of the Russian Federation within a state assignment for the Federal Scientific Research Center “Crystallography and Photonics” of the Russian Academy of Sciences.

Author information

Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Federal Research Center “Crystallography and Photonics”, Russian Academy of Sciences, 119333, Moscow, Russia

    O. B. Zainullin, N. I. Sorokina, V. A. Komornikov, I. S. Timakov & A. E. Voloshin

Authors
  1. O. B. Zainullin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. I. Sorokina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. A. Komornikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. S. Timakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. E. Voloshin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. B. Zainullin.

Additional information

Translated by E. Bondareva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zainullin, O.B., Sorokina, N.I., Komornikov, V.A. et al. Synthesis, Structure, and Properties of the Tris(ethylendiamine)nickel(II) Dichloride Dihydrate [Ni(H2NCH2CH2NH2)3]Cl2 ⋅ 2H2O Crystals. Crystallogr. Rep. 66, 529–534 (2021). https://doi.org/10.1134/S1063774521030305

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774521030305

Search

Navigation