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Crystal Chemistry Study of Two Magnesium Complexes with Trifluoroacetylacetone

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Abstract

Single crystal X-ray diffraction at a temperature of 150(2) K is used to determine the structures of two magnesium complexes with trifluoroacetylacetone: [Mg(tfac)2]3I and [Mg(H2O)2(tfac)2]·H2O II. Crystallographic data for I: space group P21/n, a = 12.5226(10) Å, b = 13.0591(7) Å, c = 12.6034(13) Å, β = 95.243(2)°, V = 2052.5(3) Å3, Z = 2; for II: space group P21/c, a = 10.826(2) Å, b = 7.0742(13) Å, c = 21.858(4) Å, β = 102.712(5)°, V = 1632.9(5) Å3, Z = 4. The isle structure of I is formed by linear trimeric molecules; in the structure of II the molecules of the complex and crystallization water form a layered framework using hydrogen bondings; the coordinated water molecules are in a trans position. The magnesium atoms have a distorted octahedral coordination environment, the Mg–O distances are 1.991(4)- 2.146(4) Å and 2.040(5)-2.073(5) Å in molecules of I and II respectively.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    N. V. Kuratieva, E. S. Vikulova & K. V. Zherikova

  2. Novosibirsk State University, Novosibirsk, Russia

    N. V. Kuratieva

Authors
  1. N. V. Kuratieva
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  2. E. S. Vikulova
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  3. K. V. Zherikova
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Correspondence to N. V. Kuratieva.

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Original Russian Text © 2018 N. V. Kuratieva, E. S. Vikulova, K. V. Zherikova.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 135–139, January–February, 2018.

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Kuratieva, N.V., Vikulova, E.S. & Zherikova, K.V. Crystal Chemistry Study of Two Magnesium Complexes with Trifluoroacetylacetone. J Struct Chem 59, 131–135 (2018). https://doi.org/10.1134/S0022476618010195

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  • DOI: https://doi.org/10.1134/S0022476618010195

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