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Metal–Organic Frameworks of Magnesium Based on 2,5-Dihydroxy-3,6-di-tert-butyl-para-benzoquinone

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Abstract

New one-dimensional metal−organic frameworks of magnesium [Mg(pQ)·2DMF]n (I), [Mg(pQ)·2DMAA]n (II), and [Mg(pQ)·2(NMP)]n (III) (pQ is the 2,5-dihydroxy-3,6-di-tert-butyl-para-benzoquinone dianion) are synthesized by the solvothermal method in different solvents (N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMAA), and N-methyl-2-pyrrolidone (NMP)). The crystal structures of compounds I and III are determined by X-ray structure analysis (CIF files CCDC nos. 2058147 (I) and 2058148 (II)). The spectral characteristics and thermal stability of the synthesized metal−organic frameworks are studied.

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ACKNOWLEDGMENTS

The studies were carried out using the equipment of the Analytical Center of the Razuvaev Institute of Organometallic Chemistry (Russian Academy of Sciences). Electronic absorption spectra recording was supported by the Ministry of Science and Higher Education of the Russian Federation using the scientific equipment of the Scientific Technical Center for Raman Spectroscopy of the Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences). The X-ray diffraction data were obtained on the Belok beamline at the Kurchatov specialized source of synchrotron radiation of the Kurchatov Institute Russian Research Center.

Funding

This work was supported by the Russian Foundation for Basic Research, project no. 18-29-04041-mk.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    O. Yu. Trofimova, I. V. Ershova, A. V. Maleeva & A. V. Piskunov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    I. A. Yakushev

  3. Kurchatov Institute Russian Research Center, 123182, Moscow, Russia

    I. A. Yakushev & P. V. Dorovatovskii

  4. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    R. R. Aisin

Authors
  1. O. Yu. Trofimova
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  2. I. V. Ershova
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  3. A. V. Maleeva
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  4. I. A. Yakushev
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  5. P. V. Dorovatovskii
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  6. R. R. Aisin
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  7. A. V. Piskunov
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Correspondence to A. V. Piskunov.

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Translated by E. Yablonskaya

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Trofimova, O.Y., Ershova, I.V., Maleeva, A.V. et al. Metal–Organic Frameworks of Magnesium Based on 2,5-Dihydroxy-3,6-di-tert-butyl-para-benzoquinone. Russ J Coord Chem 47, 610–619 (2021). https://doi.org/10.1134/S1070328421090086

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  • DOI: https://doi.org/10.1134/S1070328421090086

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