Abstract
Platinum(II) complexes cis-[Pt(NH3)2I2] (1) and trans-[Pt(NH3)2(N3)2] (2) are structurally characterized separately for the first time. The crystallographic data are as follows: for 1, a = 7.0065(6) Å, b = 6.8714(6) Å, c = 7.4106(8) Å, β = 108.432(7)°, space group P21/m, Z = 2, ρcalc = 4.739 g/cm3; for 2, a = 8.1337(5) Å, b = 11.5821(7) Å, c = 6.9705(5) Å, β = 107.256(2)°, space group P21/c, Z = 4, ρcalc = 3.318 g/cm3. Platinum atoms have a square planar environment; the main structure-forming factor is the presence of intermolecular hydrogen bonds forming chain motifs in the structure of 1 and a threedimensional framework in the structure of 2.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
F. S. Mackay, J. A. Woods, P. Heringova, J. Kasparkova, A. M. Pizarro, S. A. Moggach, S. Parsons, V. Brabec, and P. J. Sadler, Proc. Natl. Acad. Sci. 104, No. 52, 20743–20748 (2007).
R. E. Doherty, I. V. Sazanovich, L. K. McKenzie, A. S. Stasheuski, R. Coyle, E. Baggaley, S. Bottomley, J. A. Weinstein, and H. E. Bryant, Sci. Rep. 6, 22668–22676 (2016).
N. A. Kratochwil, J. A. Parkinson, P. J. Bednarski, and P. J. Sadler, Angew. Chem., Int. Ed. 38, No. 10, 1460–1463 (1999).
F. S. Mackay, J. A. Woods, H. Moseley, J. Ferguson, A. Dawson, S. Parsons, and P. J. Sadler, Chem.–Eur. J. 12, No. 11, 3155–3161 (2006).
N. A. Kratochwil, M. Zabel, K.-J. Range, and P. J. Bednarski, J. Med. Chem., 39, No. 13, 2499–2507 (1996).
S. C. Dhara, Indian J. Chem. 8, 193/194 (1970).
A. I. Smolentsev, A. I. Gubanov, A. V. Zadesenets, P. E. Plyusnin, I. A. Baidina, and S. V. Korenev, J. Struct. Chem., 51, No. 4, 709–713 (2010).
G. Sheldrick, Acta Cryst. Sec. A 64, No. 1, 112–122 (2008).
Bruker, SADABS, Bruker AXS Inc, Madison, Wisconsin, USA (2001).
G. Raudaschl-Sieber, B. Lippert, J. F. Britten, and A. L. Beauchamp, Inorg. Chim. Acta 124, No. 4, 213–217 (1986).
G. H. W. Milburn and M. R. Truter, J. Chem. Soc. A Inorg. Phys. Theor., 2, 1609–1616 (1966).
V. Kahlenberg, T. Gelbrich, R. Tessadri, and F. Klauser, Acta Crystallogr. Sect. E 71, No. 4, 366–370 (2015).
W. B. Connick and H. B. Gray, Acta Crystallogr. Sec. C 50, No. 7, 1040–1042 (1994).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2017 D. B. Vasilchenko, A. V. Zadesenets, I. A. Baidina, D. A. Piryazev, G. V. Romanenko.
Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 8, pp. 1739-1742, November-December, 2017.
Rights and permissions
About this article
Cite this article
Vasilchenko, D.B., Zadesenets, A.V., Baidina, I.A. et al. Crystal structures of cis-diiododiammine platinum and trans-diazidodiammine platinum. J Struct Chem 58, 1689–1692 (2017). https://doi.org/10.1134/S0022476617080315
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476617080315