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Stoichiography in the study of spatial heterogeneity of the chemical composition and structure of thin films and nanostructured systems

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Abstract

We present the principles of stoichiography and a reference-free stoichiographic differential (separating) dissolution method used to study the composition and structure of thin films and nanostructured systems: HTS films with 123 different compositions, Al–Au–Sn–Co–Mn, Si/SiO2/Ni(Cr)–Cu–Cu2S, Cr–Cu–S, and Cu–S multilayer films, Bi–Ti–O films on Ru/SiO2/Si, Mn1–xZn x S, and ZnS–EuS supports, and also nanostructured manganese ferrite in borate glass matrices, nanodisperse composite sorbents and the Co–Si–Pt–O/Al2O3 catalyst modified by Pt nanoparticles, and oxide catalyst precursor Fe2Co/Al2O3 for the synthesis of carbon nanotubes.

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References

  1. V. V. Malakhov, Dokl. AN SSSR, 290, No. 5, 1152 (1986).

    CAS  Google Scholar 

  2. V. V. Malakhov and I. G. Vasilyeva, Usp. Khim. 77, No. 4, 370–392 (2008).

    Article  Google Scholar 

  3. V. V. Malakhov, in: Voltammetry: Theory, Types and Applications, Yuki Saito and Takumi Kikuchi (eds.), Nova Science Publishers, New York (2014), pp. 43–85.

  4. V. V. Malakhov, Zh. Anal. Khim. 72, No. 6, 1–15 (2017).

    Google Scholar 

  5. I. G. Vasilyeva, A. A. Vlasov, Ya. I Gibner, and V. V. Malakhov, Dokl. AN, 324, No. 3, 596 (1992).

    Google Scholar 

  6. I. G. Vasilyeva, A. A. Vlasov, V. V. Malakhov, and M. R. Predtechensky, Thin Solid Films 292, 85–90 (1997).

    Article  CAS  Google Scholar 

  7. V. G. Bessergenev, E. N. Ivanova, Yu. A. Kovalevskaya, S. A. Gromilov, V. N. Kirichenko, S. M. Zemskova, and I. G. Vasilieva, Mat. Res. Bull. 30, No. 11, 1393–1400 (1995).

    Article  CAS  Google Scholar 

  8. V. G. Bessergenev, E. N. Ivanova, Yu. A. Kovalevskaya, I. G. Vasilieva, V. L. Varand, S. M. Zemskova, S. V. Larionov, B. A. Kolesov, B. M. Ayupov, and V. A. Logvinenko, Mat. Res. Bull. 32, No. 10, 1403–1410 (1997).

    Article  CAS  Google Scholar 

  9. I. G. Vasilyeva, E. N. Ivanova, A. A. Vlasov, and V. V. Malakhov, Mater. Res. Bull. 38, No. 3, 409–420 (2003).

    Article  CAS  Google Scholar 

  10. I. G. Vasilyeva, L. S. Dovlitova, V. I. Zaikovskii, V. V. Malakhov, I. S. Edel′man, A. S. Stepanov, and K. S. Aleksandrov, Dokl. AN 401, No. 3, 349–352 (2005).

    Google Scholar 

  11. L. G. Gordeeva, A. V. Gubar′, L. M. Plyasova, V. V. Malakhov, and Yu. I. Aristov, Kinet. Katal. 46, No. 5, 780–786 (2005).

    Article  Google Scholar 

  12. L. G. Gordeeva, I. S. Glaznev, E. V. Savchenko, V. V. Malakhov, and Y. I. Aristov, J. Colloid Interface Sci., 301, 685–691 (2006).

    Article  CAS  Google Scholar 

  13. L. S. Dovlitova, A. A. Pochtar′, and V. V. Malakhov, J. Struct. Chem., 55, No. 6, 1166–1171 (2014).

    Article  CAS  Google Scholar 

  14. V. V. Malakhov and V. N. Parmon, Dokl. AN 466, No. 1, 55–58 (2016).

    Google Scholar 

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. V. Malakhov

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  1. V. V. Malakhov
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Correspondence to V. V. Malakhov.

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Original Russian Text © 2017 V. V. Malakhov.

Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 8, pp. 1602-1609, November-December, 2017.

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Malakhov, V.V. Stoichiography in the study of spatial heterogeneity of the chemical composition and structure of thin films and nanostructured systems. J Struct Chem 58, 1551–1559 (2017). https://doi.org/10.1134/S002247661708011X

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  • DOI: https://doi.org/10.1134/S002247661708011X

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