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Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II)

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Abstract

[Pd(acacdmpda)] complex (1) is obtained for the first time by the interaction of [Pd(CH3CN)2Cl2], NaOH, and H2acacdmpda (acacdmpda = N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato-)) in acetonitrile. The compound is characterized by elemental analysis and IR spectroscopy; its structure is determined by single crystal X-ray diffraction. Complex 1 has a molecular structure. The coordination environment of the Pd2+ cation is a distorted square formed by O and N atoms of the tetradentately coordinated acacdmpda2– ligand. The average Pd–O and Pd–N bond lengths are 1.998(4) Å and 2.016(4) Å respectively. The N–Pd–O chelate angles are 92.34(10)° and 91.73(9)°; the N–Pd–N angle is 95.52(10)°. The thermal properties of 1 are studied by thermogravimetry. The complex passes quantitatively into the gas phase in the temperature range 225-325 °С.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. A. Cherkasov, E. S. Vikulova, N. S. Nikolaeva, A. I. Smolentsev & N. B. Morozova

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    S. A. Cherkasov & A. I. Smolentsev

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  1. S. A. Cherkasov
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  2. E. S. Vikulova
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  3. N. S. Nikolaeva
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  4. A. I. Smolentsev
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  5. N. B. Morozova
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Correspondence to A. I. Smolentsev.

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Original Russian Text © 2017 S. A. Cherkasov, E. S. Vikulova, N. S. Nikolaeva, A. I. Smolentsev, N. B. Morozova.

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Cherkasov, S.A., Vikulova, E.S., Nikolaeva, N.S. et al. Crystal structure and thermal properties of N,N′-(2,2-dimethylpropylene)-bis(acetylacetoneiminato)palladium(II). J Struct Chem 58, 1453–1456 (2017). https://doi.org/10.1134/S0022476617070277

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  • DOI: https://doi.org/10.1134/S0022476617070277

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