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Structure of bis(citrato)germanates with different types of cations: (Hphen)2[Ge(HCit)2·3H2O], [CuCl(phen)2]2[Ge(HCit)2·6H2O], where H4Cit is citric acid, phen IS 1,10-phenanthroline

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Abstract

The procedures are developed and the complexation products are preparatively isolated from GeO2–H4Cit-phen–CH3CN–H2O (I) and GeO2–H4Cit–CuCl2-phen–C2H5OH–H2O (II) systems (phen is 1,10-phenanthroline, H4Cit is citric acid). The (Hphen)2[Ge(HCit)2]·3H2O (I) and [Cu(phen)2Cl]2[Ge(HCit)2]·6H2O (II) complexes are characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. The compounds are formed from centrosymmetric octahedral [Ge(HCit)2]2– anions, Hphen+ (I) and [Cu(phen)2Cl]+ (II) cations, and crystallization water molecules. The structural units in the crystals are linked via a system of hydrogen bonds.

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Authors and Affiliations

  1. Mechnikov Odessa National University, Odessa, Ukraine

    I. I. Seifullina, E. E. Martsinko, E. A. Chebanenko & O. V. Pirozhok

  2. Scientific and Technological Complex “Institute for Single Crystals”, National Academy of Sciences, Kharkov, Ukraine

    V. V. Dyakonenko & S. V. Shishkina

  3. Karazin Kharkov National University, Kharkiv, Ukraine

    S. V. Shishkina

Authors
  1. I. I. Seifullina
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  2. E. E. Martsinko
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  3. E. A. Chebanenko
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  4. O. V. Pirozhok
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  5. V. V. Dyakonenko
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  6. S. V. Shishkina
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Correspondence to I. I. Seifullina.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 3, pp. 560-566, March-April, 2017.

Original Russian Text © 2017 I. I. Seifullina1, E. E. Martsinko, E. A. Chebanenko, O. V. Pirozhok, V. V. Dyakonenko, S. V. Shishkina.

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Seifullina, I.I., Martsinko, E.E., Chebanenko, E.A. et al. Structure of bis(citrato)germanates with different types of cations: (Hphen)2[Ge(HCit)2·3H2O], [CuCl(phen)2]2[Ge(HCit)2·6H2O], where H4Cit is citric acid, phen IS 1,10-phenanthroline. J Struct Chem 58, 532–538 (2017). https://doi.org/10.1134/S0022476617030143

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