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Synthesis, thermal stability, and structure of bis(citrato)germanates: [Co(Phen)3][Ge(HCit)2] · 2H2O, [Fe(Phen)3][Ge(HCit)2] · 4H2O (H4Cit = citric acid, Phen = 1,10-phenanthroline)

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Abstract

Synthetic procedures were developed and the complexes [Fe(Phen)3][Ge(HCit)2] · 4H2O (I) and [Co(Phen)3][Ge(HCit)2] · 2H2O (II) (Phen is 1,10-phenanthroline, H4Cit is citric acid) were obtained. The identity, composition, and thermal stability of the complexes were established by elemental analysis, thermogravimetry, and IR spectroscopy. According to X-ray diffraction data (CIF files CCDC nos. 1515837 (I) and 1515838 (II)), complexes I and II are different-metal cation–anion complexes with the same bis(citrato)germanate anion Ge(HCit)2]2–. The charge of the complex anions is counterbalanced by the octahedral complex cations, [Fe(Phen)3]2+ (I) or [Co(Phen)3]2+ (II).

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Authors and Affiliations

  1. Mechnikov Odessa National University, Odessa, 65082, Ukraine

    I. I. Seifullina, E. E. Martsinko, E. A. Chebanenko & O. V. Pirozhok

  2. State Scientific Institution “Institute for Single Crystals”, National Academy of Sciences of Ukraine, Kharkiv, 61001, Ukraine

    V. V. Dyakonenko & S. V. Shihkina

  3. Karazin Kharkiv National University, Kharkiv, 61022, Ukraine

    S. V. Shihkina

Authors
  1. I. I. Seifullina
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  2. E. E. Martsinko
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  3. E. A. Chebanenko
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  4. O. V. Pirozhok
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  5. V. V. Dyakonenko
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  6. S. V. Shihkina
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Corresponding author

Correspondence to E. E. Martsinko.

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Original Russian Text © I.I. Seifullina, E.E. Martsinko, E.A. Chebanenko, O.V. Pirozhok, V.V. Dyakonenko, S.V. Shihkina, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 8, pp. 476–481.

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Seifullina, I.I., Martsinko, E.E., Chebanenko, E.A. et al. Synthesis, thermal stability, and structure of bis(citrato)germanates: [Co(Phen)3][Ge(HCit)2] · 2H2O, [Fe(Phen)3][Ge(HCit)2] · 4H2O (H4Cit = citric acid, Phen = 1,10-phenanthroline). Russ J Coord Chem 43, 505–511 (2017). https://doi.org/10.1134/S1070328417080061

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  • DOI: https://doi.org/10.1134/S1070328417080061

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