Abstract
The X-ray diffraction study of new derivatives of perchlorate (9Н-xanthene-9-yl) and (4H-chromen-4-yl) triphenyl phosphonium is performed. It is demonstrated that the change in the molecular structure leading to a change in the degree of benzoannelation does not affect the phosphorus–carbon bond length. It is determined that perchlorate (2-phenyl-4Н-chromen-4-yl) triphenyl phosphonium сrystallizes as two polymorphs.
Similar content being viewed by others
References
P. P. Onysko and G. G. Gololobov, Russ. J. Gen. Chem., 49, No. 1, 39 (1979).
T. J. Alavosus and D. A. Sweigart, J. Am. Chem. Soc., 107, 985 (1985).
S. V. Krivun, Dokl. Akad. Nauk., 182, No. 2, 347 (1968).
G. Doddi and G. Ercolani, J. Org. Chem., 51, 4385 (1986).
V. T. Abaev, L. I. Kisarova, A. A. Bumber, I. E. Mikhailov, S. E. Emanuilidi, and O. Yu. Okhlobystin, Dokl. Akad. Nauk., 301, No. 2, 359 (1988).
G. E. Ivanov and G. V. Pavlyuk, Russ. J. Gen. Chem., 57, No. 5, 1128 (1987).
M. Hori, T. Kataoka, Yu. Asahi, and E. Mizuta, Chem. Pharm. Bull., 21, No. 7, 1415 (1973).
M. A. Kostogryz, A. A. Bumber, V. V. Profatilova, V. V. Tkachev, and A. N. Utenyshev, “IV International Conference on New Technologies and Applications of Modern Physical and Chemical Methods (NMR, Chromatography/Mass-Spectroscopy, IR–Fourier Spectroscopy and Their Combinations) for the Study of Environment, including Sections for Young Scientists of Research and Educational Centers of Russia”, Rostov-on-Don (2007).
Y. K. Yung and J. Tae, Org. Lett., 25, No. 7, 5721 (2006).
A. A. Ladatko, A. A. Bumber, I. D. Sadekov, A. A. Arutyunyants, V. I. Braslavets, and E. I. Sadekov, USSR Authors’ Certificate, No. 1735295 (1992).
V. T. Abaev, L. I. Kisarova, S. E. Emanuilidi, I. E. Mikhailov, I. B. Klark, A. I. Yanovsky, Yu. T. Struchkov, and O. Yu. Okhlobystin, Izv. AN SSSR, 59, No. 7, 1506 (1989).
G. M. Sheldrik, SHELX-86, Program for the Сrystal Structurе Determination, University of Cambridge, England (1986).
G. M. Sheldrik, SHELXTL v. 6.14, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA (2000).
А. Gavezzotti, Crystal. Rev., 7, 5 (1998).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 1, pp. 113-118, January-February, 2017.
Original Russian Text © 2017 A. N. Utenyshev, V. V. Tkachev, N. S. Tkacheva, A. A. Bumber.
Rights and permissions
About this article
Cite this article
Utenyshev, A.N., Tkachev, V.V., Tkacheva, N.S. et al. Crystal and molecular structure of the derivatives of perchlorate (4Н-chromen-4-yl) and (9Н-xanthene-9-yl) triphenyl phosphonium. J Struct Chem 58, 107–112 (2017). https://doi.org/10.1134/S0022476617010164
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476617010164