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Crystal and molecular structure of the derivatives of perchlorate (4Н-chromen-4-yl) and (9Н-xanthene-9-yl) triphenyl phosphonium

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Abstract

The X-ray diffraction study of new derivatives of perchlorate (9Н-xanthene-9-yl) and (4H-chromen-4-yl) triphenyl phosphonium is performed. It is demonstrated that the change in the molecular structure leading to a change in the degree of benzoannelation does not affect the phosphorus–carbon bond length. It is determined that perchlorate (2-phenyl-4Н-chromen-4-yl) triphenyl phosphonium сrystallizes as two polymorphs.

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References

  1. P. P. Onysko and G. G. Gololobov, Russ. J. Gen. Chem., 49, No. 1, 39 (1979).

    CAS  Google Scholar 

  2. T. J. Alavosus and D. A. Sweigart, J. Am. Chem. Soc., 107, 985 (1985).

    Article  CAS  Google Scholar 

  3. S. V. Krivun, Dokl. Akad. Nauk., 182, No. 2, 347 (1968).

    CAS  Google Scholar 

  4. G. Doddi and G. Ercolani, J. Org. Chem., 51, 4385 (1986).

    Article  CAS  Google Scholar 

  5. V. T. Abaev, L. I. Kisarova, A. A. Bumber, I. E. Mikhailov, S. E. Emanuilidi, and O. Yu. Okhlobystin, Dokl. Akad. Nauk., 301, No. 2, 359 (1988).

    CAS  Google Scholar 

  6. G. E. Ivanov and G. V. Pavlyuk, Russ. J. Gen. Chem., 57, No. 5, 1128 (1987).

    CAS  Google Scholar 

  7. M. Hori, T. Kataoka, Yu. Asahi, and E. Mizuta, Chem. Pharm. Bull., 21, No. 7, 1415 (1973).

    Article  Google Scholar 

  8. M. A. Kostogryz, A. A. Bumber, V. V. Profatilova, V. V. Tkachev, and A. N. Utenyshev, “IV International Conference on New Technologies and Applications of Modern Physical and Chemical Methods (NMR, Chromatography/Mass-Spectroscopy, IR–Fourier Spectroscopy and Their Combinations) for the Study of Environment, including Sections for Young Scientists of Research and Educational Centers of Russia”, Rostov-on-Don (2007).

    Google Scholar 

  9. Y. K. Yung and J. Tae, Org. Lett., 25, No. 7, 5721 (2006).

    Article  Google Scholar 

  10. A. A. Ladatko, A. A. Bumber, I. D. Sadekov, A. A. Arutyunyants, V. I. Braslavets, and E. I. Sadekov, USSR Authors’ Certificate, No. 1735295 (1992).

    Google Scholar 

  11. V. T. Abaev, L. I. Kisarova, S. E. Emanuilidi, I. E. Mikhailov, I. B. Klark, A. I. Yanovsky, Yu. T. Struchkov, and O. Yu. Okhlobystin, Izv. AN SSSR, 59, No. 7, 1506 (1989).

    CAS  Google Scholar 

  12. G. M. Sheldrik, SHELX-86, Program for the Сrystal Structurе Determination, University of Cambridge, England (1986).

    Google Scholar 

  13. G. M. Sheldrik, SHELXTL v. 6.14, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA (2000).

    Google Scholar 

  14. А. Gavezzotti, Crystal. Rev., 7, 5 (1998).

    Article  CAS  Google Scholar 

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Correspondence to A. N. Utenyshev.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 58, No. 1, pp. 113-118, January-February, 2017.

Original Russian Text © 2017 A. N. Utenyshev, V. V. Tkachev, N. S. Tkacheva, A. A. Bumber.

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Utenyshev, A.N., Tkachev, V.V., Tkacheva, N.S. et al. Crystal and molecular structure of the derivatives of perchlorate (4Н-chromen-4-yl) and (9Н-xanthene-9-yl) triphenyl phosphonium. J Struct Chem 58, 107–112 (2017). https://doi.org/10.1134/S0022476617010164

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  • DOI: https://doi.org/10.1134/S0022476617010164

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