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Organic-inorganic hybrid perovskite (C6H5(CH2)2NH3)2CdCl4: Synthesis, structural and thermal properties

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Abstract

The present research work reports the study on crystal structure, vibrational spectroscopy and thermal analysis of organic-inorganic hybrid compound (C6H5(CH2)2NH3)2CdCl4. Single crystals of bis(phenethylammonium)tetrachlorocadmate (C6H5(CH2)2NH3)2CdCl4 (PEA–Cd) were obtained by diffusion at room temperature. This compound crystallizes in the orthorhombic space group C2cb with unit cell parameters a = 7.4444(2) Å, b = 38.8965(3) Å, c = 7.3737(2) Å and Z = 4. Single crystal structure has been solved and refined to R = 0.036 and wR = 0.092. The structure consists of an extended [CdCl4]2– network and two [C6H5(CH2)2NH3]+ cations to form a two-dimensional perovskite system. The infrared (IR) spectrum of the title compound was recorded at room temperature. Differential scanning calorimetry (DSC) was used to investigate the phase transition; this compound exhibits a reversible single solid-solid phase transition.

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Authors and Affiliations

  1. Laboratoire de Physique des Matériaux et Modélisation des Systèmes, CNRST-URAC08, Faculté des Sciences, Université Moulay Ismail, B.P. 11201, Zitoune, 50000, Meknès, Maroc

    S. Kassou & A. Belaaraj

  2. Physics Department, College of Sciences and Humanity, Prince Sattam bin Abdulaziz University, P.O. Box 83, Al-Kharj, 11942, Saudi Arabia

    A. Kaiba

  3. CNRS, Université Bordeaux, ICMCB, UPR 9048, F-33600, Pessac, France

    P. Guionneau

Authors
  1. S. Kassou
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  2. A. Kaiba
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  3. P. Guionneau
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  4. A. Belaaraj
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Correspondence to A. Belaaraj.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 776-781, May-June, 2016.

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Kassou, S., Kaiba, A., Guionneau, P. et al. Organic-inorganic hybrid perovskite (C6H5(CH2)2NH3)2CdCl4: Synthesis, structural and thermal properties. J Struct Chem 57, 737–743 (2016). https://doi.org/10.1134/S0022476616040168

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