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X-ray diffraction study of the monoclinic modification of [Cu(NH3)4](ReO4)2 in the range 100-410 K

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Abstract

The monoclinic modification of [Cu(NH3)4](ReO4)2 complex salt in the range 100-410 K is studied by single crystal X-ray diffraction. The crystallographic data for 300 K are as follows: a = 10.6123(3) Å, b = 7.5443(2) Å, c = 15.2261(4) Å, β = 108.406(1)°, V = 1156.67(5) Å3, space group Р21/n, Z = 4, d x = 3.623 g/cm3. The coordination environment of the Cu atom, being a distorted square formed by four nitrogen atoms with Cu–N of 1.997-2.018 Å, is completed by the contacts with two oxygen atoms Cu…O of 2.472 Å and 2.598 Å. The comparative crystal chemical analysis with the triclinic modification of [Cu(NH3)4](ReO4)2 known in the literature is performed.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. A. Gromilov, S. P. Khranenko, D. A. Piryazev & N. V. Kuratieva

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    S. A. Gromilov, D. A. Piryazev & N. V. Kuratieva

Authors
  1. S. A. Gromilov
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  2. S. P. Khranenko
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  3. D. A. Piryazev
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  4. N. V. Kuratieva
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Corresponding author

Correspondence to S. A. Gromilov.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 764-769, May-June, 2016.

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Gromilov, S.A., Khranenko, S.P., Piryazev, D.A. et al. X-ray diffraction study of the monoclinic modification of [Cu(NH3)4](ReO4)2 in the range 100-410 K. J Struct Chem 57, 725–730 (2016). https://doi.org/10.1134/S0022476616040144

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  • DOI: https://doi.org/10.1134/S0022476616040144

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