Skip to main content
SpringerLink
Log in

X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2] n transformation

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The X-ray in-situ study of [Cu(NH3)4](ReO4)2 complex salt is carried out on heating up to 500 K. The product obtained at this temperature is a new crystalline phase [Cu(NH3)2(μ-ReO4)2] n with the following unit cell parameters: a = 14.7523(3) Å, b = 5.8559(1) Å, c = 5.6290(1) Å, β = 111.387(1)°, V = = 452.799(2) Å3, space group C2/m, Z = 2, d x = 4.386 g/cm3. The coordination polyhedron of the Cu atom is a distorted octahedron formed by two nitrogen atoms (Cu–N 2.195 Å), and four oxygen atoms (Cu–О 2.306 Å). The structure consists of infinite [Cu(NH3)2(μ-ReO4)2] n chains, the shortest N(H)…O distances between the chains being 2.82 Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. I. Gubanov, Double Complexes with Tetrammine Cations as Precursors of Metal Powders [in Russian], Cand. Sci. (Chem.) Dissertation Theses, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk (2002).

    Google Scholar 

  2. S. V. Korenev, Synthesis, Structure and Physicochemical Properties of Double Complex Salts of Platinum-Group Metals with Ammonia and Halogenide Ions [in Russian], Doctoral (Chem.) Dissertation Theses, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk (2003).

    Google Scholar 

  3. K. V. Yusenko, Double Complex Salts of Hexachloro-(Bromo)metallates(IV) (Ir, Pt, Os, Re) Chloropentammine Rhodium(III) and Iridium(III) [in Russian], Cand. Sci. (Chem.) Dissertation Theses, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk (2005).

    Google Scholar 

  4. A. V. Zadesenets, Synthesis and Physicochemical Research of Complex Salts–Precursors of Ultrafine Metal Powders Containing Pt, Pd and Some Basic Metals [in Russian], Cand. Sci. (Chem.) Dissertation Theses, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk (2008).

    Google Scholar 

  5. P. E. Plyusnin Synthesis and Physico-Chemical Studies of Complexes of Tetrachlorometallates of Pd(II), Pt(II) and Au(III) [in Russian], Cand. Sci. (Chem.) Dissertation Theses, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk (2009).

    Google Scholar 

  6. E. Yu. Filatov Production and X-Ray Investigation of Nanosized Bimetallic Powders Containing Platinum-Group Metals [in Russian], Cand. Sci. (Chem.) Dissertation Theses, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk (2009).

    Google Scholar 

  7. Yu. V. Shubin, Formation and Structural-Phase Transformations of Nanosized Bimetallic Particles Based on Noble Metals [in Russian], Doctoral Sci. (Chem.) Dissertation Theses, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk (2009).

    Google Scholar 

  8. S. A. Martynova, E. Yu. Filatov, S. V. Korenev, et al., J. Solid State Chem., 212, 42–47 (2014).

    Article  CAS  Google Scholar 

  9. O. Wittke, Acta Crystallogr., A49, Suppl., 265 (1993).

    Article  Google Scholar 

  10. S. P. Khranenko, E. A. Shusharina, S. A. Gromilov, and A. I. Smolentsev, J. Struct. Chem., 50, No. 6, 1201–1203 (2009).

    Article  CAS  Google Scholar 

  11. G. M. Sheldrick, Acta Crystallogr., A 64, No. 1, 112–122 (2008).

    Article  CAS  Google Scholar 

  12. W. Kraus and G. Nolze, J. Appl. Crystallogr., 29, 301–303 (1996).

    Article  CAS  Google Scholar 

  13. PDF-2. Powder Diffraction File, International Centre for Diffraction Data, Pennsylvania, USA (2009).

  14. Inorganic Crystal Structure Database (ICSD). Release 2014, Fashinformationszentrum Karlsruhe, D-1754, Eggenstein-Leopoldshafen, Germany (2014).

  15. A. Butz, G. Miehe, H. Paulus, P. Strauss, and H. Fuess, J. Solid State Chem., 138, 232–237 (1998).

    Article  CAS  Google Scholar 

  16. A. Altomare, C. Cuocci, C. Giacovazzo, A. Moliterni, R. Rizzi, N. Corriero, and A. Falcicchio, J. Appl. Crystallogr., 46, 1231–1235 (2013).

    Article  CAS  Google Scholar 

  17. A. C. Larson and R. B. Von Dreele, General Structure Analysis System (GSAS), Report LAUR 86-748, Los Alamos National Laboratory (2004).

    Google Scholar 

  18. B. H. Toby, J. Appl. Crystallogr., 34, 210–213 (2001).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. A. Gromilov, D. A. Piryazev, P. E. Plyusnin & S. V. Korenev

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    S. A. Gromilov, D. A. Piryazev, P. E. Plyusnin & S. V. Korenev

  3. Institute of Solid State Chemistry, Urals Branch, Russian Academy of Sciences, Ekaterinburg, Russia

    A. P. Tyutyunnik

Authors
  1. S. A. Gromilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. P. Tyutyunnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. A. Piryazev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. E. Plyusnin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. V. Korenev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. A. Gromilov.

Additional information

Original Russian Text © 2016 S. A. Gromilov, A. P. Tyutyunnik, D. A. Piryazev, P. E. Plyusnin, S. V. Korenev.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gromilov, S.A., Tyutyunnik, A.P., Piryazev, D.A. et al. X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO4)2] n transformation. J Struct Chem 57, 140–145 (2016). https://doi.org/10.1134/S0022476616010170

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476616010170

Keywords

Search

Navigation