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Crystal structure of [Rh(H2O)5Cl](C7H7O3S)2 and Cs[Rh(H2O)5NO3](C7H7O3S)3•H2O

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Abstract

The crystal structures of the compounds with the composition [Rh(H2O)5Cl](C7H7O3S)2 (I) and Cs[Rh(H2O)5NO3](C7H7O3S)3•H2O (II) are determined. Crystallographic data for I: a = 10.063(10) Å, b = 7.771(8) Å, c = 13.524(15) Å; β = 100.44(3)°, space group P21, Z = 2, d calc = 1.823 g/cm3; for II: a = 16.221(3) Å, b = 9.646(19) Å, c = 21.307(4) Å, β = 92.06(3)°, space group P21, Z = 8, d calc = 1.833 g/cm3. The compounds are characterized by IR spectroscopy and powder X-ray diffraction. The rhodium atoms have a distorted octahedral environment consisting of five oxygen atoms of coordinated water molecules and one chloride ion (I)/oxygen atom of the nitrate ion (II) with the following distances: Rh–OH2O of 1.993-2.075 Å and Rh–Cl of 2.270 Å for I; Rh–\({O_{{H_2}O}}\) of 1.996-2.031 Å and Rh–\({O_{N{O_3}}}\) of 1.990 Å for II.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. N. Vorobieva, I. A. Baidina, A. V. Belyaev, I. V. Korolkov & N. I. Alferova

  2. Novosibirsk National Research State University, Moscow, Russia

    S. N. Vorobieva & I. V. Korolkov

Authors
  1. S. N. Vorobieva
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  2. I. A. Baidina
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  3. A. V. Belyaev
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  4. I. V. Korolkov
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  5. N. I. Alferova
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Correspondence to S. N. Vorobieva.

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Original Russian Text © 2015 S. N. Vorobieva, I. A. Baidina, A. V. Belyaev, I. V. Korolkov, N. I. Alferova.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 56, No. 8, pp. 1668-1674, December, 2015.

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Vorobieva, S.N., Baidina, I.A., Belyaev, A.V. et al. Crystal structure of [Rh(H2O)5Cl](C7H7O3S)2 and Cs[Rh(H2O)5NO3](C7H7O3S)3•H2O. J Struct Chem 56, 1606–1612 (2015). https://doi.org/10.1134/S0022476615080235

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  • DOI: https://doi.org/10.1134/S0022476615080235

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