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Synthesis and structure of R 2[UO2(NO3)2(NCS)2] (R = Rb or Cs)

  • Structure of Inorganic Compounds
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Abstract

Crystals Rb2[UO2(NO3)2(NCS)2] (I) and Cs2[UO2(NO3)2(NCS)2] (II) have been synthesized and studied by IR spectroscopy and X-ray diffraction. Crystals I are monoclinic, with the following parameters: a = 12.2118(5) Å, b = 10.2545(3) Å, c = 11.8754(4) Å, β = 110.287(1)°, sp. gr. C2/c, Z = 4, and R = 0.0523. Crystals II are orthorhombic, with a = 13.7309(3) Å, b = 10.5749(2) Å, c = 10.1891(2) Å, sp. gr. Pnma, Z = 4, and R = 0.0411. The basic structural units of crystals I and II are one-core complexes [UO2(NO3)2(NCS)2]2−, which belong to the crystallochemical group cis-AB 012 M 12 (A = UO 2+2 , B 01 = NO −3 , M 1 = NCS−), which are combined into a framework via electrostatic interactions with ions of alkaline metals R (R = Rb or Cs). The structural features of crystals I and II, which condition the formation of [UO2(NO3)2(NCS)2]2− complexes with a cis rather than a trans position of isothiocyanate ions in the coordination sphere of uranyl ions, are discussed.

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References

  1. Inorganic Crystal Structure Database (The National Institute of Standards and Technology (NIST) and Fachinformationszentrum (FIZ), Karlsruhe, 2012).

  2. Cambridge Structural Database System. Version 5.30 (Crystallographic Data Centre, Cambridge, 2013).

  3. I. A. Charushnikova and K. Den Over, Koord. Khim. 33(1), 55 (2007).

    Google Scholar 

  4. P. Thuery and M. Nierlich, J. Chem. Soc., Dalton Trans., No. 9, 1481 (1997).

    Google Scholar 

  5. P. C. Leverd, I. Dumazet-Bonnamour, R. Lamartine, and M. Nierlich, Chem. Commun., No. 6, 493 (2000).

    Google Scholar 

  6. B. Masci and P. Thuery, New J. Chem. 29(3), 493 (2005).

    Article  Google Scholar 

  7. V. N. Serezhkin, A. V. Vologzhanina, L. B. Serezhkina, et al., Acta Crystallogr. B 65(1), 45 (2009).

    Article  Google Scholar 

  8. J. M. Farmer, J. A. Kautz, H. S. Kwon, and D. F. Mullica, J. Chem. Cryst. 30(5), 301 (2000).

    Article  Google Scholar 

  9. G. M. Sheldrick, SADABS. Program for Empirical X-Ray Absorption Correction (Bruker-Nonius, 1990–2004).

    Google Scholar 

  10. Bruker SHELXTL. Version 6.22 (Bruker AXS, Madison, WI, 2005).

  11. V. N. Serezhkin, Yu. N. Mikhailov, and Yu. A. Buslaev, Zh. Neorg. Khim. 42(12), 2036 (1997).

    Google Scholar 

  12. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Wiley, New York, 1986; Mir, Moscow, 1991).

    Google Scholar 

  13. Yu. Ya. Kharitonov, G. V. Tsintsadze, and A. Yu. Tsivadze, Zh. Neorg. Khim. 15(5), 1196 (1970).

    Google Scholar 

  14. G. L. Caldow, A. B. Van Cleave, and R. L. Eager, Can. J. Chem. 38(6), 772 (1960).

    Article  Google Scholar 

  15. R. R. Shuvalov and P. C. Burns, Acta Crystallogr. 59(8), i71 (2003).

    Google Scholar 

  16. O. V. Osetska, I. V. Raspertova, A. V. Khavryuchenko, et al., Polyhedron 24(13), 1631 (2005).

    Article  Google Scholar 

  17. P. Thuery, Cryst. Growth Des. 8(11), 4132 (2008).

    Article  Google Scholar 

  18. L. B. Serezhkina, A. V. Vologzhanina, E. S. Klynin, et al., Crystallogr. Rep. 57(2), 258 (2012).

    Article  ADS  Google Scholar 

  19. J. C. Taylor and M. H. Mueller, Acta Crystallogr. 19(4), 536 (1965).

    Article  Google Scholar 

  20. R. N. Shchelokov, Yu. N. Mikhailov, G. M. Lobanova, et al., Zh. Neorg. Khim. 27(9), 2348 (1982).

    Google Scholar 

  21. K. A. Hughes and P. C. Burns, Acta Crystallogr. C 59(1), i7 (2003).

    Article  Google Scholar 

  22. I. Weissbuch, R. Popovitz-Biro, M. Lahav, and L. Leiserowitz, Acta Crystallogr. B 51(2), 115 (1995).

    Article  Google Scholar 

  23. I. Weissbuch, M. Lahav, and L. Leiserowitz, Cryst. Growth Des. 3(2), 125 (2003).

    Article  Google Scholar 

  24. N. K. Dalley, M. H. Mueller, and S. H. Simonsen, Inorg. Chem. 10(2), 323 (1971).

    Article  Google Scholar 

  25. J. C. Taylor and M. H. Mueller, Acta Crystallogr. 19(4), 536 (1965).

    Article  Google Scholar 

  26. Yu. N. Mikhailov, L. B. Sveshnikova, A. S. Kanishcheva, et al., Zh. Neorg. Khim. 54(12), 1978 (2009).

    Google Scholar 

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Authors and Affiliations

  1. Samara State University, ul. Akademika Pavlova 1, Samara, 443011, Russia

    V. N. Serezhkin, V. A. Grigor’eva & L. B. Serezhkina

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. V. Peresypkina & A. V. Virovets

Authors
  1. V. N. Serezhkin
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  2. E. V. Peresypkina
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  3. V. A. Grigor’eva
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  4. A. V. Virovets
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  5. L. B. Serezhkina
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Correspondence to V. N. Serezhkin.

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Original Russian Text © V.N. Serezhkin, E.V. Peresypkina, V.A. Grigor’eva, A.V. Virovets, L.B. Serezhkina, 2015, published in Kristallografiya, 2015, Vol. 60, No. 1, pp. 51–56.

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Serezhkin, V.N., Peresypkina, E.V., Grigor’eva, V.A. et al. Synthesis and structure of R 2[UO2(NO3)2(NCS)2] (R = Rb or Cs). Crystallogr. Rep. 60, 46–51 (2015). https://doi.org/10.1134/S1063774515010204

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  • DOI: https://doi.org/10.1134/S1063774515010204

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