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Spin-crossover in coordination compounds of iron(II) with tris(pyrazol-1-yl)methane and cluster anions

  • Structure and Properties of Coordination Compounds
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Abstract

Synthesis procedures for new coordination compounds of iron(II) with tris(pyrazol-1-yl)methane (HC(pz)3), containing cluster anions in the outer sphere, of the composition [Fe{HC(pz)3}2][Mo6Cl14]•2H2O (I), [Fe{HC(pz)3}2][Mo6Br14]•H2O (II), and [Fe{HC(pz)3}2]2[Re6S8(CN)6]•2H2O (III) are developed. The compounds are studied by static magnetic susceptibility, electronic, IR, and Mössbauer spectroscopic methods. The magnetochemical study shows that in the polycrystalline phases of all compounds the spincrossover 1 А 1 ⇔ 5 Т 2 is observed which is accompanied by thermochromism.

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Authors and Affiliations

  1. Komsomolsk-on-Amur State Technical University, Moscow, Russia

    O. G. Shakirova

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    L. G. Lavrenova, E. V. Korotaev, L. A. Sheludyakova, V. A. Varnek, M. A. Shestopalov & Yu. V. Mironov

  3. Novosibirsk National Research State University, Moscow, Russia

    L. G. Lavrenova, L. A. Sheludyakova, M. A. Shestopalov & Yu. V. Mironov

Authors
  1. O. G. Shakirova
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  2. L. G. Lavrenova
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  3. E. V. Korotaev
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  4. L. A. Sheludyakova
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  5. V. A. Varnek
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  6. M. A. Shestopalov
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  7. Yu. V. Mironov
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Correspondence to O. G. Shakirova.

Additional information

Original Russian Text © 2015 O. G. Shakirova, L. G. Lavrenova, E. V. Korotaev, L. A. Sheludyakova, V. A. Varnek, M. A. Shestopalov, Yu. V. Mironov.

Translated from Zhurnal Strukturnoi Khimii, Vol. 56, No. 8, pp. 1581-1587, December, 2015.

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Shakirova, O.G., Lavrenova, L.G., Korotaev, E.V. et al. Spin-crossover in coordination compounds of iron(II) with tris(pyrazol-1-yl)methane and cluster anions. J Struct Chem 56, 1520–1526 (2015). https://doi.org/10.1134/S0022476615080090

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  • DOI: https://doi.org/10.1134/S0022476615080090

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