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Spin Crossover—An Overall Perspective

  • Chapter
Spin Crossover in Transition Metal Compounds I

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 233))

Abstract

In this chapter an outline is presented of the principal features of electronic spin crossover. The development of the subject is traced and the various modes of manifestation of spin transitions are presented. The role of cooperativity in influencing solid state behaviour is considered and the various strategies to strengthen it are addressed along with the chemical and physical perturbations which affect crossover behaviour. The role of intermediate spin states is discussed together with spin crossover in five-coordinate systems. The various techniques applied to monitoring a transition are presented briefly. An introduction to theoretical treatments is given and likely areas for future developments are suggested. Relevant review articles in the field are listed and reference to later chapters in the series is given where appropriate.

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Abbreviations

abpt:

4-Amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole

bpy:

2,2′-Bipyridine

btr:

4,4′-Bis(1,2,4-triazole)

Cp :

Heat capacity

DSC:

Differential scanning calorimetry

EPR:

Electron paramagnetic resonance

HS:

High spin

LS:

Low spin

LIESST:

Light induced excited spin state trapping

mephen:

2-Methyl-1,10-phenanthroline

NIESST:

Nuclear decay induced excited spin state trapping

NMR:

Nuclear magnetic resonance

ox:

The oxalate ion

paptH:

2-(Pyridin-2-yl-amino)-4-(pyridin-2-yl)thiazole

phen:

1,10-Phenanthroline

phy:

1,10-Phenanthroline-2-carbaldehyde phenylhydrazone

pic:

2-Picolylamine

PM-BiA:

N-(2-Pyridylmethylene)aminobiphenyl

ptz:

1-n-Propyl-tetrazole

py:

Pyridine

SCO:

Spin crossover

ST:

Spin transition

T1/2 :

Spin transition temperature (temperature of 505% conversion of all “SCO-active” complex molecules)

TCNQ:

Tetracyanodiquinomethane

trpy:

2,2′:6′,2″-Terpyridine

trzH:

1,2,4-Triazole

ZFS:

Zero field splitting

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  1. Institut für Anorganische Chemie und Analytische Chemie, Johannes-Gutenberg-Universität, Staudinger Weg 9, 55099, Mainz, Germany

    Philipp Gütlich

  2. School of Chemical Sciences, University of New South Wales, 2052, Sydney, NSW, Australia

    Harold A. Goodwin

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Gütlich, P., Goodwin, H.A. Spin Crossover—An Overall Perspective. In: Gütlich, P., Goodwin, H. (eds) Spin Crossover in Transition Metal Compounds I. Topics in Current Chemistry, vol 233. Springer, Berlin, Heidelberg. https://doi.org/10.1007/b13527

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