Skip to main content
SpringerLink
Log in

Crystal structures and characterization of two one-dimensional coordination polymers containing Ln3+ ions and anthranilate (C7H6NO −2 ) anions

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The syntheses, crystal structures and characterization (IR, TGA/DSC) of the isostructural one-dimensional coordination polymers [Ce(C7H6NO2)3] n (1) and [Pr(C7H6NO2)3] n (2) are described. The metal ions adopt distorted capped square anti-prismatic MO9 coordination geometries. The anthranilate ligands bridge the metal ions in bridging-bidentate (O, μ2-O′) mode to generate [010] chains in the crystal and each ligand features an intramolecular N-H⋯O hydrogen bond. It is notable that two very similar, but crystallographically distinct chains appear in the unit cell. Crystal data: 1, C21H18CeN3O6, M r = 548.51, monoclinic, P21/c (No. 14), a = 25.0476(10) Å, b = 7.4924(2) Å, c = 24.6366(7) Å, β = 119.424(1)°, V = 4027.1(2) Å3, R(F) = 0.037, wR(F 2) = 0.068. 2, C21H18N3O6Pr, M r = 549.29, monoclinic, P21/c (No. 14), a = 25.0077(13) Å, b = 7.4497(3) Å, c = 24.6063(12) Å, β = 119.392(2)°, V = 3994.1(3) Å3, R(F) = 0.031, wR(F 2) = 0.068.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. J. Brown, Proc. Roy. Soc. Lond., A302, 185–199 (1968).

    Article  Google Scholar 

  2. A. Mukherjee, M. K. Saha, M. Nethaji, and A. R. Chakravarty, Polyhedron, 23, 2177–2182 (2004).

    Article  CAS  Google Scholar 

  3. N. Palanisami and R. Murugavel, Inorg. Chim. Acta, 365, 430–438 (2011).

    Article  CAS  Google Scholar 

  4. F. M. Nie, M. Li, W. Liu, G. X. Li, and T. Fang, Z. Kristallogr. — New Cryst. Struct., 224, 446–448 (2009).

    CAS  Google Scholar 

  5. S. M. Boudreau, R. A. Boudreau, and H. M. Haendler, J. Solid State Chem., 49, 379–384 (1983).

    Article  CAS  Google Scholar 

  6. L. Jin, S. Lu, and S. Lu, Polyhedron, 15, 4069–4077 (1996).

    Article  CAS  Google Scholar 

  7. G. B. Deacon, M. Forsyth, P. C. Junk, S. G. Leary, and G. J. Moxey, Polyhedron, 25, 379–386 (2006).

    Article  CAS  Google Scholar 

  8. G. M. Sheldrick, SADABS, University of Gottingen, Germany.

  9. G. M. Sheldrick, A Short History of SHELX, Acta Crystallogr., A64, 112–122 (2008).

    Article  Google Scholar 

  10. L. J. Farrugia, ORTEP-3 for Windows — a version of ORTEP-III with a Graphical User Interface (GUI), J. Appl. Crystallogr., 30, 565 (1997).

    CAS  Google Scholar 

  11. W. Chen and S. Fukuzumi, Inorg. Chem., 48, 3800–3807 (2009).

    Article  CAS  Google Scholar 

  12. R. Swisłocka, E. Regulska, M. Samsonowicz, T. Hrynaszkiewicz, and W. Lewandowski, Spectrochim. Acta, A61, 2966–2973 (2005).

    Article  Google Scholar 

  13. R. Murugavel, V. V. Karambelkar, G. Anantharaman, and M. G. Walawalkar, Inorg. Chem., 39, 1381–1390 (2000).

    Article  CAS  Google Scholar 

  14. G. S. Singh and T. Pheko, Spectrochim. Acta, A70, 595–600 (2008).

    Article  Google Scholar 

  15. I. D. Brown and D. Altermatt, Acta Crystallogr., B41, 244–247 (1985).

    Article  CAS  Google Scholar 

  16. C. D. Martin, R. I. Smith, W. G. Marshall, and J. B. Parise, Am. Mineral., 92, 1912–1918 (2007).

    Article  CAS  Google Scholar 

  17. R. Koner, M. Nayak, G. Ferguson, J. N. Low, C. Glidewell, P. Misra, and S. Mohanta, Crystallogr. Eng. Comm., 7, 129–132 (2005).

    Article  CAS  Google Scholar 

  18. A. L. Spek, J. Appl. Crystallogr., 36, 7–13 (2003).

    Article  CAS  Google Scholar 

  19. J. Z. Gu, J. Wu, D. Y. Lv, Y. Tang, K. Zhu, and J. Wu, Dalton Trans., 4822–4830 (2013).

  20. W. Brzyska and Z. Rzaczynska, Pol. J. Chem., 60, 27–36 (1986).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Government College University, Lahore, Pakistan

    S. Hussain & I. U. Khan

  2. Department of Chemistry, University of Aberdeen, Aberdeen, Scotland

    William T. A. Harrison

  3. Department of Physics, University of Sargodha, Sargodha, Pakistan

    M. N. Tahir

  4. Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan

    S. Ahmad

Authors
  1. S. Hussain
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. U. Khan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. William T. A. Harrison
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. N. Tahir
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. Ahmad
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Hussain.

Additional information

Original Russian Text © 2015 S. Hussain, I. U. Khan, William T. A. Harrison, M. N. Tahir, S. Ahmad.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 1, pp. 133–140, January–February, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hussain, S., Khan, I.U., Harrison, W.T.A. et al. Crystal structures and characterization of two one-dimensional coordination polymers containing Ln3+ ions and anthranilate (C7H6NO −2 ) anions. J Struct Chem 56, 126–133 (2015). https://doi.org/10.1134/S0022476615010187

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476615010187

Keywords

Search

Navigation