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Crystal structures of two one-dimensional coordination polymers constructed from Mn2+ ions, chelating hexafluoro-acetylacetonate anions, and flexible bipyridyl bridging ligands

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Abstract

The syntheses and crystal structures of two one-dimensional coordination polymers, [Mn(C5HO2F6)2(C16H20N2)] n (1) and [Mn(C5HO2F6)2(C20H20N2)] n (2), are described, where C5HO2F6 − is the hexafluoro acetylacetonate anion, C16H20N2 is 1,6-bis(4-pyridyl)-hexane, and C20H20N2 is 1,4-bis[2-(3-pyridyl)ethyl]-benzene. In both phases, the metal ion lies on a crystallographic twofold axis and is coordinated by two chelating C5HO2F6 − anions and two bridging bipyridyl ligands to generate a cis-MnN2O4 octahedron. The bridging ligands, which are completed by crystallographic inversion symmetry in both compounds, connect the metal nodes into zigzag [20 1 ] chains in 1 and contorted [001] chains in 2. Intrachain C–H•••O interactions occur in 1 but not in 2, which may be correlated with the relative orientations of the ligands. Crystal data: 1, C26H22F12MnN2O4, M r = 709.40, monoclinic, C2/c (No. 15), a = 9.3475(2) Å, b = 16.6547(3) Å, c = 18.3649(4) Å, β = 91.1135(8)°, V = 2858.50(10) Å3, Z = 4, R(F) = 0.030, w R(F 2) = 0.075. 2, C30H22F12MnN2O4, M r = 757.44, monoclinic, C2/c (No. 15), a = 19.9198(2) Å, b = 10.6459(2) Å, c = 16.8185(3) Å, β = 119.8344(8)°, V = 3093.91(9) Å3, Z = 4, R(F) = 0.032, w R(F 2) = 0.078.

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Authors and Affiliations

  1. Department of Chemistry, University of Aberdeen, Aberdeen, Scotland

    M. J. Plater, B. M. De Silva, M. R. St. J. Foreman & W. T. A. Harrison

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  1. M. J. Plater
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  2. B. M. De Silva
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  3. M. R. St. J. Foreman
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  4. W. T. A. Harrison
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Correspondence to W. T. A. Harrison.

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Original Russian Text © 2016 M. J. Plater, B. M. De Silva, M. R. St. J. Foreman, W. T. A. Harrison.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 6, pp. 1230-1235, July-August, 2016.

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Plater, M.J., De Silva, B.M., Foreman, M.R.S.J. et al. Crystal structures of two one-dimensional coordination polymers constructed from Mn2+ ions, chelating hexafluoro-acetylacetonate anions, and flexible bipyridyl bridging ligands. J Struct Chem 57, 1169–1175 (2016). https://doi.org/10.1134/S0022476616060160

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  • DOI: https://doi.org/10.1134/S0022476616060160

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