Abstract
In the reaction of (Et4N)2[W2S4Cl4] with 1,2-bis(diphenylphosphino)ethane in acetonitrile a new binuclear complex of tungsten(V) [W2S4Cl2(dppe)2]·2CH3CN is obtained. Its crystal structure is solved in the triclinic space group P-1 with the following unit cell parameters a = 10.1202(16) Å, b = 11.758(2) Å, c = 12.648(2) Å, α = 104.324(5)°, β = 106.469(5)°, γ = 97.587(5)°, V = 1364.9(4) Å3, Z = 1, with the final refinement parameters R 1 = 0.0545, wR 2 = 0.1053. The work describes the synthesis, crystal structure, and Raman spectrum of the [W2S4Cl2(dppe)2]·2CH3CN complex.
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Original Russian Text © 2015 S. B. Artemkina, A. Yu. Ledneva, D. A. Piryazev, A. V. Virovets, Yu. V. Mironov, V. E. Fedorov.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 56, No. 1, pp. 128–132, January–February, 2015.
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Artemkina, S.B., Ledneva, A.Y., Piryazev, D.A. et al. Structure of a new binuclear complex of tungsten [W2S4Cl2(dppe)2]·2CH3CN. J Struct Chem 56, 121–125 (2015). https://doi.org/10.1134/S0022476615010175
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DOI: https://doi.org/10.1134/S0022476615010175