Skip to main content
SpringerLink
Log in

Copper(II) complexes with Schiff bases: Structures and thermal behavior

  • Crystal Chemistry
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Ligands with Schiff bases are obtained in the condensation of propylenediamine (pda) or 2,2-dimethylpropylenediamine (dmpda) with acetylacetone (Hacac) in the 1:2 molar ratio. The ligands are characterized by the elemental analysis methods, T melt = 90–92 °C for pda(Hacac)2 (pda(acac)2 is N,N′-propylene-bis(acetylacetoniminato) (2-)), T melt = 84–86 °C for dmpda(Hacac)2 (dmpda(acac)2 is N,N′-2,2-dimethylpropylene-bis(acetylacetoniminato) (2-)). The tautomerism of the ligands is established by the single crystal X-ray diffraction (XRD) analysis, IR spectroscopy, and 1H, 13C NMR spectrometry. The synthesized complexes [Cu(pda(acac)2)] (1), T melt = 121–122 °C and [Cu(dmpda(acac)2)] (2), T melt = 156–158 °C are studied by the XRD method. In both complexes, copper atoms have a planar square geometry, and the chelate bond lengths and angles are: Cu-O ≈ Cu-N 1.903(2)–1.942(3) Å, ∠O-Cu-N = 94.44(12)–94.99(12)° for 1 and Cu-O ≈ Cu-N 1.909(1)–1.943(2) Å, ∠O-Cu-N = 94.63(6)° for 2. By the thermogravimetric method it is found that both complexes can be passed practically quantitatively into the gas phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. H. Leung and C. M. Che, Inorg. Chem., 28, 4116–4120 (1989).

    Article  Google Scholar 

  2. N. S. Enikolopyan, K. A. Bogdanova, and K. A. Askarov, Russ. Chem. Rev., 52, 13–18 (1983).

    Article  Google Scholar 

  3. A. M. El-Hendawy, A. H. Alkubaisi, A. El-Ghany, K. El-Kourashy, and M. N. Sharab, Polyhedron, 12, 2343–2347 (1993).

    Article  CAS  Google Scholar 

  4. P. J. McCarthy, R. J. Hovey, K. Ueno, and A. E. Martell, J. Am. Chem. Soc., 77, 5820–5825 (1955).

    Article  CAS  Google Scholar 

  5. N. Aksuner, E. Henden, I. Yilmaz, and A. Cukurovali, Dyes Pigm., 83, 211–216 (2009).

    Article  CAS  Google Scholar 

  6. Y-P. Cai, C-Y. Su, A-W. Xu, B-S. Kang, Y-X. Tong, H-Q. Liu, and S. Jie, Polyhedron, 20, 657–661 (2001).

    Article  CAS  Google Scholar 

  7. G. V. Girichev, N. I. Giricheva, N. P. Kuz’mina, Yu. S. Medvedev, and A. Yu. Rogachev, J. Struct. Chem., 49, No. 5, 837–849 (2008).

    Article  CAS  Google Scholar 

  8. N. V. Tverdova, E. D Pelevina., N. I. Giricheva, G. V. Girichev, N. P. Kuzmina, and O. V. Kotova, J. Mol. Struct., 1012, 151–161 (2012).

    Article  CAS  Google Scholar 

  9. G. V. Girichev, N. I. Giricheva, N. P. Kuz’mina, and O. V. Kotova, J. Struct. Chem., 50, No. 1, 52–59 (2009).

    Article  Google Scholar 

  10. R. C. Charles, J. Phys. Chem., 65, No. 3, 3383–3390 (1961).

    Article  Google Scholar 

  11. Yu. V. Chumachenko, Chem. Sc. Candidate’s Diss., 02.00.01, Novosibirsk (1979).

    Google Scholar 

  12. G. I. Zharkova, S. I. Dorovskikh, S. V. Sysoev, I. P. Asanov, A. V. Panin, N. B. Morozova, and I. K. Igumenov, Surf. Coat. Techn., 230, 290–296 (2013).

    Article  CAS  Google Scholar 

  13. R. G. Charles, Thermochim. Acta, 38, 315–327 (1980).

    Article  CAS  Google Scholar 

  14. P. A. Premkumar, R. Pankajavalli, O. M. Sreedharan, V. S. Raghunathan, K. S. Nagaraja, and C. Mallika, Mater. Lett., 58, 2256–2260 (2004).

    Article  Google Scholar 

  15. S. Arockiasamy, P. A. Premkumar, R. Pankajavalli, O. M. Sreedharan, V. S. Raghunathan, K. S. Nagaraja, and C. Mallika, J. Mater. Sci., 41, 3383–3390 (2006).

    Article  CAS  Google Scholar 

  16. APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11). Bruker Advanced X-ray Solutions, Bruker AXS Inc., Madison, Wisconsin, USA (2004).

  17. G. M. Sheldrick, Acta Crystallogr., A64, No. 1, 112–122 (2008).

    Article  Google Scholar 

  18. Yue-Peng Cai, Cheng-Yong Su, An-wu Xu, Bei-Sheng Kang, Ye-Xiang Tong, Han-Qin Liu, and Sun Jie, Polyhedron, 20, 657–662 (2001).

    Article  CAS  Google Scholar 

  19. A. E. Martell, R. N. Belford, and M. Calvin, J. Inorg. Nucl. Chem., 5, 170–176 (1958).

    Article  CAS  Google Scholar 

  20. S. I. Dorovskikh, A. V. Alexeyev, N. V. Kuratieva, T. V. Basova, V. G. Kiselev, L. A. Sheludyakova, Yu. V. Shubin, N. B. Morozova, and I. K. Igumenov, J. Organomet. Chem.; doi.org/10.1016/j.jorganchem.2013.05.001.

  21. G. C. Percy and D. A. Thornton, J. Inorg. Nucl. Chem., 34, 3357–3362 (1972).

    Article  CAS  Google Scholar 

  22. D. N. Kendall, Applied Infrared Spectroscopy, Reinhold Publishing, New York (1966).

    Google Scholar 

  23. S. M. Abn-EI-Wafa, R. A. Issa, and C. A. McAuliffe, Inorg. Chim. Acta, 99, 103–113 (1985).

    Article  Google Scholar 

  24. W. S. Rees and C. R. Caballero, Adv. Mater. Optic. Electron., 1, 59–63 (1992).

    Article  CAS  Google Scholar 

  25. I. A. Baidina, P. A. Stabnikov, A. D. Vasilèv, S. A. Gromilov, and I. K. Igumenov, J. Struct. Chem., 45, No. 4, 671–677 (2004).

    Article  CAS  Google Scholar 

  26. P. A. Stabnikov, G. I. Zharkova, I. A. Baidina, S. V. Tkachev, V. V. Krisyuk, and I. K. Igumenov, Polyhedron, 26, 4445–4449 (2007).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. I. Dorovskikh, N. V. Kuratieva, S. V. Tkachev, S. V. Trubin, P. A. Stabnikov & N. B. Morozova

Authors
  1. S. I. Dorovskikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. V. Kuratieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Tkachev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. V. Trubin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. A. Stabnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. B. Morozova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. I. Dorovskikh.

Additional information

Original Russian Text © 2014 S. I. Dorovskikh, N. V. Kuratieva, S. V. Tkachev, S. V. Trubin, P. A. Stabnikov, N. B. Morozova.

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 6, pp. 1124–1131, November–December, 2014.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dorovskikh, S.I., Kuratieva, N.V., Tkachev, S.V. et al. Copper(II) complexes with Schiff bases: Structures and thermal behavior. J Struct Chem 55, 1067–1074 (2014). https://doi.org/10.1134/S0022476614060092

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476614060092

Keywords

Search

Navigation