Abstract
A rhenium cluster complex (2,2′-bipyH2)2[Re4Se4(CN)12] · (2,2′-bipy)·7H2O (1) is obtained and characterized. The compound crystallizes in a monoclinic space group C2/c with the unit cell parameters: a = 16.9191(6) Å, b = 18.7458(6) Å, c = 19.0139(5) Å, β = 108.568(1)°, V = 5716.6(3) Å3, Z = 4, d x = 2.291 g/cm3. The crystal structure is a packing of bipyridylium cations (2,2′-bipyH2)2+, cluster anions [Re4Se4(CN)12]4−, bipyridyl molecules, and crystal water molecules, which are linked together by a system of hydrogen bonds.
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Original Russian Text © 2014 Ya. M. Gaifulin, A. I. Smolentsev, Yu. V. Mironov.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 5, pp. 966–968, September–October, 2014.
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Gaifulin, Y.M., Smolentsev, A.I. & Mironov, Y.V. Crystal structure of the ionic cluster complex (2,2′-bipyH2)2[Re4Se4(CN)12]·(2,2′-bipy)·7H2O. J Struct Chem 55, 920–922 (2014). https://doi.org/10.1134/S0022476614050187
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DOI: https://doi.org/10.1134/S0022476614050187