Abstract
Two iron compounds [Fe(m-NO2phtpy)2](ClO4)2 1 and [Fe(m-Clphtpy)2](ClO4)2 2 are synthesized and their structures are determined by single crystal X-ray diffraction. Crystal data for 1 are: orthorhombic, space group Pcca, a = 25.471(4) Å, b = 10.8182(18) Å, c = 14.682(2) Å, Z = 4. Crystal data for 2 are: orthorhombic, space group Pnna, a = 14.521(2) Å, b = 23.980(4) Å, c = 23.142(4) Å, and Z = 8. The iron atoms are coordinated by six N atoms from two terpyridines in both compounds. These two compounds are all linked by hydrogen bonds with C as donor and O as acceptor into a 3D network for 1 and a 2D network for 2. If viewed along the c direction in 1 and the a direction in 2, both compounds show the ordered figure with terpyridine overlapped as a square and the phenyl rings overlapped as a rectangle or a square.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Y. Fan, L. Y. Zhang, F. R. Dai, et al., Inorg. Chem., 47, 2811–2819 (2008).
P. Misra, C. Y. Liao, H. H. Wei, et al., Polyhedron, 27, 1185–1192 (2008).
K. van der Schilden, F. GarcÌa, H. Kooijman, et al., Angew. Chem. Int. Ed., 43, 5668–5670 (2004).
P. R. Andres and U. S. Schubert, Adv Mater., 16, 1043–1068 (2004).
J. Wang and G. S. Hanan, Synlett., 1251–1254 (2005).
S. C. Yuan, H. B. Chen, and H. C. Wang, Progress in Chemistry (Chin. Ed.), 21, 2132–2152 (2009).
Y. Q. Tao, E. C. Constable, C. E. Housecroft, et al., Polyhedron, 33, 267–272 (2012).
J. McMurtrie and I. Dance, CrystEngComm., 11, 1141–1149 (2009).
E. A. Medlycott, G. S. Hanan, T. S. M. Abedin, et al., Polyhedron, 27, 493–501 (2008).
W. W. Fu, D. Z. Kuang, F. X. Zhang, et al., Chinese J. Inorg. Chem. (Chin. Ed.), 29, 654–658 (2013).
Y. H. Wang, D. X. Zhang, G. R. Qiang, et al., Zhejiang Chemical Industry (Chin. Ed.), 26, 16–19 (1995).
G. M. Sheldrick, SHELXS-97 and SHELXL-97, Univ. Göttingen, Germany (1998).
G. M. Sheldrick, Acta Crystallogr., A64, 112–122 (2008).
A. Morsali, H. H. Monfared, A. Ramazani, et al., J. Coord. Chem., 62, 2631–2640 (2009).
W. Huang and H. Qian, J. Mol. Struct., 874, 64–76 (2008).
J. E. Beves, D. J. Bray, J. K. Clegg, et al., Inorg. Chim. Acta, 361, 2582–2590 (2008).
N. W. Alcock, P. R. Barker, J. M. Haider, et al., J. Chem. Soc., Dalton Trans., 1447–1461 (2000).
D. Li, Q. Zhang, P. Wang, et al., Dalton Trans., 8170–8178 (2011).
M. L. Scudder, H. A. Goodwin, and I. G. Dance, New J. Chem., 23, 695–705 (1999).
K. Moth-Poulsen, J. Bendix, P. Hammershøj, et al., Acta Crystallogr., C65, m14–m16 (2009).
R. J. Davidson, E. W. Ainscough, A. M. Brodie, et al., Inorg. Chem., 51, 8307–8316 (2012).
C. Bhaumik, S. Das, D. Maity, et al., Dalton Trans., 11795–11808 (2011).
E. C. Constable, M. Neuburger, D. R. Smith, et al., Chem. Commun., 1917/1918 (1996).
P. Liu, Y. Liu, and E. L. M. Wong, Chem. Sci., 2, 2187–2195 (2011).
N. M. Logacheva, V. E. Baulin, A. Y. Tsivadze, et al., Dalton Trans., 2482–2489 (2009).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2014 W.-W. Fu, F.-X. Zhang, D.-Z. Kuang.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 5, pp. 941–946, September–October, 2014.
Rights and permissions
About this article
Cite this article
Fu, W.W., Zhang, F.X. & Kuang, D.Z. Syntheses and crystal structures of [Fe(m-NO2phtpy)2](ClO4)2 and [Fe(m-Clphtpy)2](ClO4)2 (m-NO2phtpy = 4′-(3-nitrophenyl)-2,2′:6′,2″-terpyridine and m-Clphtpy = 4′-(3-chlorophenyl)-2,2′:6′,2″-terpyridine). J Struct Chem 55, 895–900 (2014). https://doi.org/10.1134/S002247661405014X
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S002247661405014X