Abstract
The possibility of a simultaneous use of X-ray diffraction and X-ray absorption techniques in order to characterize the sizes, shapes, and chemical composition of grains in a sample (the solution of the extended uncertainty problem due to the Babinet principle) is shown. A sample of the GaAs0.7Se0.3/GaAs solid solution is investigated on the developed laboratory device for a simultaneous performance of X-ray diffraction and X-ray absorption experiments. It is shown that the GaAs0.7Se0.3 sample decomposes into separate GaAs and GaSe domains forming a mosaic structure. The sizes of GaAs and GaSe domains are estimated. Components with a linear geometry are sometimes revealed in the composition of GaSe grains.
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Original Russian Text © 2014 M. D. Sharkov, M. E. Boiko, A. M. Boiko, A. V. Bobyl, S. G. Konnikov.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 4, pp. 821–825, July–August, 2014.
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Sharkov, M.D., Boiko, M.E., Boiko, A.M. et al. Small-angle X-ray studies of the GaAs0.7Se0.3 solid solution at energies close to as and Se absorption edges. J Struct Chem 55, 786–790 (2014). https://doi.org/10.1134/S0022476614040301
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DOI: https://doi.org/10.1134/S0022476614040301