Skip to main content
SpringerLink
Log in

Yttrium(III) complex with 1,10-phenanthroline: Crystal structure and spectroscopic studies

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

YCl3·6H2O reacts with 1,10-phenanthroline (phen) to yield a complex of 1:2 yttrium:ligand stoichiometry. The yttrium(III) complex is characterized by the elemental analysis, UV-Vis, IR as well as the X-ray diffraction analysis. The crystal of [Y(phen)2Cl(H2O)3]Cl2·H2O obtained from a methanol solution crystallizes in the triclinic system, space group P 337-1, Z = 2, a = 10.3236(4) Å, b = 10.4566(4) Å, c = 12.5270(5) Å, α = 97.354(2)°, β = 108.740(2)°, γ = 93.458(2)°, R int = 0.046. The Y(III) ion is eight-coordinated by four nitrogen, three oxygen atoms and one chlorine atom.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. K. Boudalis, V. Nastopoulos, and S. P. Perlepes, Trans. Met. Chem., 26, 276–281 (2001).

    Article  CAS  Google Scholar 

  2. S. Mishra, L. G. Hubert-Pfalzgraf, M. Rolland, and H. Chermette, Inorg. Chem. Commun., 10, 15–19 (2007).

    Article  CAS  Google Scholar 

  3. J. Feng, H.-J. Zhang, S.-Y. Song, Z.-F. Li, L.-N. Sun, Y. Xing, and X.-M. Guo, J. Luminescence, 128, 1957–1964 (2008).

    Article  CAS  Google Scholar 

  4. S. P. Babailov and V. L. Varand, J. Struct. Chem., 50, No. 2, 348–350 (2009).

    Article  CAS  Google Scholar 

  5. W.-X. Li, L. Guo, L.-J. Chen, and X.-Y. Shi, J. Fluoresc., 18, 1043–1049 (2008).

    Article  CAS  Google Scholar 

  6. F. A. Hart and F. P. Laming, J. Inorg. Nucl. Chem., 27, 1605–1610 (1965).

    Article  CAS  Google Scholar 

  7. G. M. Sheldrick, SHELXS, SHELXL, Univ. Göttingen, Germany (1997).

    Google Scholar 

  8. A. Altomare, M. C. Burla, G. Cammalli, M. Cascarano, C. Giacovazzo, A. Guagliardi, A. G. G. Moliterni, G. Polidori, and A. Spagna, SIR97: A New Tool for Crystal Structure Determination and Refinement, CNR-IRMEC, Bari, Italy (1998).

    Google Scholar 

  9. M. Khorasani-Motlagh, M. Noroozifar, S. Niroomand, and B. O. Patrick, Inorg. Chim. Acta, 383, 72–77 (2012).

    Article  CAS  Google Scholar 

  10. J.-J. Zhang, S.-L. Xu, N. Ren, and H.-Y. Zhang, Russ. J. Inorg. Chem., 53, No. 3, 397–401 (2008).

    Article  Google Scholar 

  11. N. K. Karan, S. Mitra, G. M. Golzar Hossain, and K. M. Abdul Malik, Z. Naturforsch., 57b, 736–740 (2002).

    Google Scholar 

  12. H. Guillon, S. Daniele, L. G. Hubert-Pfalzgraf, and C. Bavoux, Inorg. Chim. Acta, 304, 99–107 (2000).

    Article  CAS  Google Scholar 

  13. L. I. Semenova and A. H. White, Aust. J. Chem., 52, 571–600 (1999).

    Article  CAS  Google Scholar 

  14. A. K. Boudalis, V. Nastopoulos, C. P. Raptopoulou, A. Terzis, and S. P. Perlepes, Z. Naturforsch., 60b, 363–372 (2005).

    Google Scholar 

  15. J. Lhoste, N. Henry, T. Loiseau, and F. Abraham, Polyhedron, 30, 1289–1294 (2011).

    Article  CAS  Google Scholar 

  16. C.-H. Zhang, X.-W. Tan, D.-Z. Kuang, and X. Nie, Z. Kristallogr. NCS, 224, 321/322 (2009).

    Google Scholar 

  17. S. P. Chen, Y. X. Ren, and S. L. Gao, Russ. J. Coordinats. Chem., 34, No. 4, 301–309 (2008).

    Article  CAS  Google Scholar 

  18. A. M. Atria, J. C. Muňoz, A. Soto, M. T. Garland, and R. Baggio, Acta Crystallogr. C, C59 (2003).

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, University of Sistan & Baluchestan, Zahedan, Iran

    A. Moodi, M. Khorasani-Motlagh & M. Noroozifar

  2. Chemistry Department, University of British Columbia, Vancouver, Canada

    B. O. Patrick

Authors
  1. A. Moodi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Khorasani-Motlagh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Noroozifar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. B. O. Patrick
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Khorasani-Motlagh.

Additional information

Original Russian Text © 2014 A. Moodi, M. Khorasani-Motlagh, M. Noroozifar, B. O. Patrick.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 2, pp. 358–363, March–April, 2014.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Moodi, A., Khorasani-Motlagh, M., Noroozifar, M. et al. Yttrium(III) complex with 1,10-phenanthroline: Crystal structure and spectroscopic studies. J Struct Chem 55, 337–341 (2014). https://doi.org/10.1134/S002247661402022X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002247661402022X

Keywords

Search

Navigation