Abstract
A comparative analysis of 6,7Li NMR spectra is performed for the samples of monoclinic lithium titanate obtained at different synthesis temperatures. In the 7Li NMR spectra three lines are found, which differ in quadrupole splitting frequencies v Q and according to ab initio EFG calculations are assigned to three crystallographic sites of lithium: Li1 (v Q ∼ 27 kHz); Li2 (v Q ∼ 59 kHz); Li3 (v Q ∼ 6 kHz). The dynamics of lithium ions is studied in a wide temperature range from 300 K to 900 K. It is found that the narrowing of 7Li NMR spectra as a result of thermally activated diffusion of lithium ions in the low-temperature Li2TiO3 sample is observed at a higher temperature in comparison with a sample of high-temperature lithium titanate. Based on the analysis of 6Li NMR spectra it is assumed that there is mixed occupancy of lithium and titanium sites in the corresponding layers of the crystal structure of low-temperature lithium titanate, which hinders lithium ion transfer over regular crystallographic sites.
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Original Russian Text Copyright © 2013 by Ya. V. Baklanova, I. Yu. Arapova, I. R. Shein, L. G. Maksimova, K. N. Mikhalev, T. A. Denisova
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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, Supplement 1, pp. S113–S120, 2013.
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Baklanova, Y.V., Arapova, I.Y., Shein, I.R. et al. Charge distribution and mobility of lithium ions in Li2TiO3 from 6,7Li NMR data. J Struct Chem 54 (Suppl 1), 111–118 (2013). https://doi.org/10.1134/S002247661307010X
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DOI: https://doi.org/10.1134/S002247661307010X