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Crystal structure of a novel complex [Co(3,3′-bpbc)(H2O)3]·H2O

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Abstract

A novel coordination polymer constructed with [Co(3,3′-bpbc)(H2O)3]·H2O(I) (3,3′-bpbc = 2,2′-bipyridine-3,3′-dicarboxylic acid) is successfully synthesized at room temperature and characterized by elemental analysis and IR spectra. The crystal structure of the complex is determined by single crystal X-ray diffraction. The unit cell parameters for complex I are: a = 9.9606(11) Å, b = 9.2552(10) Å, c = 16.0258(17) Å, β = 96.731(0)°, V = 1467.2(3) Å3, Z = 4, space group P2(1)/n. In the crystal, the cobalt(II) ion adopts a hexa-coordinate environment, and the structure units aggregate together to give birth to infinite 1D chains. The 2D and 3D framework is constructed via intermolecular hydrogen bonds.

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Authors and Affiliations

  1. Department of Coordination Chemistry, Shenyang University of Chemical Technology, International Key Laboratory of Shenyang Inorganic Molecule-Based Chemical, Shenyang, P. R. China

    E. -J. Gao, L. -L. Jiang, D. Zhang, W. Jiao, T. -L. Liu, Y. -J. Zhang, G. -L. Wu & J. Xu

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  1. E. -J. Gao
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  2. L. -L. Jiang
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  3. D. Zhang
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  4. W. Jiao
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  5. T. -L. Liu
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  6. Y. -J. Zhang
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  7. G. -L. Wu
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  8. J. Xu
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Correspondence to E. -J. Gao.

Additional information

Original Russian Text Copyright © 2013 by E.-J. Gao, L.-L. Jiang, D. Zhang, W. Jiao, T.-L. Liu, Y.-J. Zhang, G.-L. Wu, J. Xu

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 54, No. 5, pp. 940–943, September–October, 2013.

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Gao, E.J., Jiang, L.L., Zhang, D. et al. Crystal structure of a novel complex [Co(3,3′-bpbc)(H2O)3]·H2O. J Struct Chem 54, 978–982 (2013). https://doi.org/10.1134/S0022476613050211

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  • DOI: https://doi.org/10.1134/S0022476613050211

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