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Polycatenate Structure and Thermal Analysis of a New 2D + 2D Cobalt(II) Coordination Polymer Based on 5-Methoxylisophthalic Acid and 3,5-Bis(imidazole-1-yl)pyridine Co-Ligands

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Abstract

A new Co(II) compound, namely [Co(CH3O-H2Ip)(Bip)] n (I) (CH3O-H2Ip = 5-methoxylisophthalic acid and Bip = 3,5-bis(imidazole-1-yl)pyridine), has been synthesized through combination of CH3O-H2Ip, Bip and Co(II) acetate under hydrothermal condition and structurally characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction (CIF file CCDC no. 977220). It crystallizes in triclinic, space group P1̅ with a = 9.764(6), b = 10.106(6), c = 11.673(7) Å, α = 104.12970°, β = 100.601(7)°, γ = 105.324(7)°, V = 1038.6(11) Å3, C20H16CoN5O5, Mr = 465.31, Z = 2, ρcalcd = 1.488 g/cm3, μ(MoKα) = 0.869 mm−1, F(000) = 476, the final R = 0.0652 and wR = 0.1530. The X-ray analysis demonstrates that compound I exhibits a 2D + 2D polyrotaxane (4, 4) net network. Moreover, the thermal analysis of compound I has also been investigated.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, 471934, P.R. China

    Y. F. Wang, J. J. Wei & X. H. Zhai

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  1. Y. F. Wang
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  2. J. J. Wei
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  3. X. H. Zhai
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Correspondence to Y. F. Wang.

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Wang, Y.F., Wei, J.J. & Zhai, X.H. Polycatenate Structure and Thermal Analysis of a New 2D + 2D Cobalt(II) Coordination Polymer Based on 5-Methoxylisophthalic Acid and 3,5-Bis(imidazole-1-yl)pyridine Co-Ligands. Russ J Coord Chem 44, 183–186 (2018). https://doi.org/10.1134/S1070328418030065

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  • DOI: https://doi.org/10.1134/S1070328418030065

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