Skip to main content
SpringerLink
Log in

Crystal structure of two complexes containing tris-(β-diketonato)magnate anion

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Single crystal XRD is used to determine the structures of the complexes (H2TMEDA)[Mg(ptac)3]2 (1, TMEDA = Me2N(CH2)2NMe2, ptac = tBuCOCHCOCF3) and (H2TMEDA)[Mg(hfac)3](hfac) (2, hfac = CF3COCHCOCF3) at a temperature of 150 K. The crystallographic data for complex 1: a = 10.2919(3) Å, b = 10.9492(4) Å, c = 15.4159(6) Å, α = 87.117(1)°, β = 89.686(1)°, γ = 79,864(1)°, space group \(P\bar 1\) Z = 1, R = 0.0573; for complex 2: a = 12.9446(2) Å, b = 23.0035(4) Å, c = 13.1473(3) Å, β = 98.779(1)°, space group P21/n, Z = 4, R = 0.0605. The structures are ionic; the metal atom coordinates six oxygen atoms of three β-diketonate ligands. The distances Mg-O in complex 1 are in the range 2.036(2)–2.0920(19) Å; the same distances in complex 2 are in the range 2.051(2)–2.076(2) Å. The spatial packing is determined by the system of hydrogen bonds between the (H2TMEDA)2+ cations and [Mg(ptac)3]− (1) or hfac− (2) anions. A thermogravimetric study of complex 1 is carried out.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. F. Hatch and G. Sutherland, J. Org. Chem., 13, No. 2, 249 (1948).

    Article  CAS  Google Scholar 

  2. Yu-W. Zhao and H. Suhr, Appl. Phys. A, 54, 451 (1992).

    Article  Google Scholar 

  3. E. S. Vikulova, K. V. Zherikova, L. N. Zelenina, et al., Key Eng. Mat., 508, 215 (2012).

    Article  CAS  Google Scholar 

  4. A. M. E. Raj, M. Jayachandran, and C. Sanjeeviraja, CIRP J. Manuf. Sci. Techn., 2, 93 (2010).

    Google Scholar 

  5. G. B. Hammond, D. C. Nonhebel, and Ch.-H. S. Wu, Inorg. Chem., 2, No. 1, 73 (1963).

    Article  CAS  Google Scholar 

  6. E. Weiss, J. Kopf, T. Gardein, et al., Chem. Ber., 118, 3529 (1985).

    Article  CAS  Google Scholar 

  7. T. Hatanpää, J. Ihanus, J. Kansikas, et al., Chem. Mater., 11, No. 7, 1846 (1999).

    Article  Google Scholar 

  8. B. Morosin, Acta Crystallogr., 22, 315 (1967).

    Article  Google Scholar 

  9. N. P. Kuz’mina, M. V. Ryazanov, S. I. Troyuanov, et al., Koordinats. Khim., 25, No. 6, 409 (1999).

    Google Scholar 

  10. N. B. Morozova, G. I. Zharkova, P. A. Stabnikov, et al., Synthesis and Physicochemical Study of β-Diketonates of Alkaline Earth Metals [in Russian], Novosibirsk (1989); (Preprint, Institute of Inorganic Chemistry, Siberian Division, USSR Academy of Sciences, No. 89-08).

    Google Scholar 

  11. T. Hatanpää, J. Kansikas, I. Mutikainen, et al., Inorg. Chem., 40, No. 4, 788 (2001).

    Article  Google Scholar 

  12. M. E. Fragala, R. G. Toro, P. Rossi, et al., Chem. Mater., 21, No. 10, 2062 (2009).

    Article  CAS  Google Scholar 

  13. I. E. Soboleva, S. I. Troyanov, and N. P. Kuz’mina, Koordinats. Khim., 22, No. 8, 579 (1996).

    Google Scholar 

  14. J. R. Babcock, D. D. Benson, A. Wang, et al., Chem. Vapor Dep., 6, No. 4, 180 (2000).

    Article  CAS  Google Scholar 

  15. L. Wang, Yu. Yang, J. Ni, et al., Chem. Mater., 17, No. 23, 5697 (2005).

    Article  CAS  Google Scholar 

  16. M. Maria, J. Selvakumar, V. S. Raghunathan, et al., Surf. Coat. Tech., 204, 222 (2009).

    Article  CAS  Google Scholar 

  17. M. R. Truter and B. L. Vickery, J. Chem. Soc., Dalton Trans., 395 (1972).

    Google Scholar 

  18. M. Z. Gurevich, T. M. Sas, N. E. Mazepova, et al., Zh. Neorg. Khim., 20, 735 (1975).

    CAS  Google Scholar 

  19. M. Z. Gurevich, B. D. Stepin, and V. V. Zelentsov, Zh. Neorg. Khim., 15, 890 (1970).

    CAS  Google Scholar 

  20. S. J. Lippard, J. Am. Chem. Soc., 88, 4800 (1966).

    Article  Google Scholar 

  21. M. Z. Gurevich, T. M. Sas, B. D. Stepin, et al., Zh. Neorg. Khim., 16, 2099 (1971).

    CAS  Google Scholar 

  22. V. P. Fadeeva and I. M. Moryakina, Izv. Sib. Otd. Akad. Nauk SSSR, Ser Khim., 6, 113 (1981).

    Google Scholar 

  23. V. P. Fadeeva, V. D. Tikhova, and O. N. Nikulicheva, J. Anal. Chem., 63, 1094 (2008).

    Article  CAS  Google Scholar 

  24. J. S. Strukl and J. L. Walter, Spectrochim. Acta A, 27, 209 (1971).

    Article  CAS  Google Scholar 

  25. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Organic Compounds, John Wiley & Sons, Inc., New York (1997).

    Google Scholar 

  26. A. Gordon and R. Ford, The Chemist’s Companion, John Wiley & Sons, New York (1972).

    Google Scholar 

  27. T. V. Basova, V. G. Kiselev, E. S. Filatov, et al., Vib. Spectroscop., 61, 219 (2012).

    Article  CAS  Google Scholar 

  28. NETZSCH Proteus Thermal Analysis v.4.8.1, Netzsch-Gerätebau, Bayern, Germany (2005).

  29. Bruker: SADABS, SAINT and SHELXTL, Bruker AXS Inc., Madison, Wisconsin, USA (2008).

  30. S. A. Gromilov and I. A. Baidina, J. Struct. Chem., 45, No. 6, 1031–1081 (2004).

    Article  CAS  Google Scholar 

  31. K. V. Zherikova, N. V. Kuratieva, I. A. Baidina, et al., J. Struct. Chem., 51, No. 6, 769 (2010).

    Article  CAS  Google Scholar 

  32. F. A. Villamena, M. H. Dickman, and D. L.R. Crist, Inorg. Chem., 37, No. 7, 1446 (1998).

    Article  CAS  Google Scholar 

  33. H. Mehdi, K. Binnemans, K. Van Hecke, et al., Chem. Commun., 46, 234 (2010).

    Article  CAS  Google Scholar 

  34. E. Yu. Fursova, O. V. Kuznetsova, V. I. Ovcharenko, et al., Izv. Akad. Nauk, Ser. Khim., 6, 1175 (2008).

    Google Scholar 

  35. S. J. Coles, J. Granifo, M. B. Hursthouse, et al., Acta Crystallogr., E57, m535 (2001).

    Google Scholar 

  36. T. S. Pochekutova, V. K. Khamylov, G. K. Fukin, et al., Polyhedron, 30, 1945 (2011).

    Article  CAS  Google Scholar 

  37. J. A. Darr, S. R. Drake, M. B. Hursthouse, et al., J. Chem. Soc., Dalton Trans., 945 (1997).

    Google Scholar 

  38. F. Marchetti, C. Pettinari, R. Pettinari, et al., Inorg. Chem., 45, No. 7, 3074 (2006).

    Article  CAS  Google Scholar 

  39. D. J. Otway and W. S. Rees Jr., Coord. Chem. Rev., 210, 279 (2000).

    Article  CAS  Google Scholar 

  40. L. Huang, S. B. Turnipseed, R. C. Haltiwanger, et al., Inorg. Chem., 33, No. 4, 798 (1994).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    E. S. Vikulova, D. A. Piryazev, K. V. Zherikova, N. I. Alferova, N. B. Morozova & I. K. Igumenov

Authors
  1. E. S. Vikulova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. A. Piryazev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. V. Zherikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. I. Alferova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. B. Morozova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. K. Igumenov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. S. Vikulova.

Additional information

Original Russian Text Copyright © 2013 by E. S. Vikulova, D. A. Piryazev, K. V. Zherikova, N. I. Alferova, N. B. Morozova, I. K. Igumenov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 54, No. 5, pp. 845–851, September–October, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vikulova, E.S., Piryazev, D.A., Zherikova, K.V. et al. Crystal structure of two complexes containing tris-(β-diketonato)magnate anion. J Struct Chem 54, 883–889 (2013). https://doi.org/10.1134/S0022476613050077

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476613050077

Keywords

Search

Navigation