Abstract
Mono- and bis-chelate iron(III)-containing complexes with a tridentate azomethine ligand based on n-dodecyloxybenzoic acid ester derivatives with oxybenzoyl-4-salidene-N′-ethyl-N-ethylenediamine with NO −3 counterions are obtained. The structure of the compounds is determined by IR spectroscopy, elemental analysis, and mass spectrometry (MALDI-ToF MS). It is found that the complexation of iron salts with tridentate ligands in a mixture of solvents (alcohol:benzene) results in the formation of bischelate compounds of the composition 1:2 with octahedral packing of iron in the complex, while in pure alcohol solutions, asymmetric mono-chelate complexes are obtained.
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Original Russian Text Copyright © 2012 by M. S. Gruzdev, U. V. Chervonova, A. M. Kolker, A. S. Golubeva
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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 5, pp. 865–871, September–October, 2012.
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Gruzdev, M.S., Chervonova, U.V., Kolker, A.M. et al. Solvent effect in the preparation of iron(III) azomethine complexes based on 4,4′-dodecyloxybenzoyloxybenzoyl-4-salicylidene-N′-ethyl-N-ethylenediamine. J Struct Chem 53, 845–850 (2012). https://doi.org/10.1134/S0022476612050046
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DOI: https://doi.org/10.1134/S0022476612050046