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A new complex of 2-aminopyridine and malonic acid in a 1:1 stoichiometric ratio is obtained. The complex crystallizes in a centrosymmetric P21/c space group with a = 3.8522(2)Å, b = 17.5226(8)Å, c = 13.7317(7)Å and β = 94.418(3)°. This complex is held by network of hydrogen bonds between the protonated 2-aminopyridinium cation and the malonate anion. There is no phase transition observed in this complex, which is verified using DSC and single crystal X-ray measurement studies. Unlike 2-aminopyridinium maleate, this complex crystallizes in the centrosymmetric space group and hence, this complex will not exhibit any non-linear optical property.
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Original Russian Text Copyright © 2012 by R. Chitra, P. Roussel, F. Capet, G. J. Abraham, R. R. Choudhury
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 53, No. 2, pp. 354–359, March–April, 2012.
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Chitra, R., Rousse, P., Capet, F. et al. Molecular interactions in 2-aminopyridinium malonate. J Struct Chem 53, 354–360 (2012). https://doi.org/10.1134/S0022476612020217
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DOI: https://doi.org/10.1134/S0022476612020217