Abstract
The crystal and molecular structure of a 1-(1-silatranylmethyl)-3,5-dimethylpyrazole complex with zinc dichloride (I) is determined by XRD. The coordination polyhedron of the zinc atom is a tetrahedron formed by two covalent Zn-Cl bonds and coordination Zn ← N and Zn ← O bonds. Compound I is the first example of how an endocyclic oxygen atom of the silatranyl fragment participates in the coordination of the metal atom with the formation of a six-membered heterocycle.
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References
V. I. Sokol, V. P. Nikolaev, L. A. Butman, et al., Zh. Neorg. Khim., 24, Vyp. 3, 727–729 (1979).
P. De Vaal, F. B. Hulsbergen, and R. A. G. de Graaff, Acta Crystallogr. (C), 39, No. 11, 1543/1544 (1983).
L. V. Baikalova, V. I. Sokol, I. A. Zyryanova, et al., Zh. Obshch. Khim., 76,Vyp. 5, 828–835 (2006).
V. I. Sokol, L. V. Baikalova, V. S. Sergienko, et al., Koordinats. Khim., 33, No. 5, 367–372 (2007).
L. V. Baikalova, V. I. Sokol, N. N. Chipanina, et al., Koordinats. Khim., 34, No. 7, 488–499 (2008).
V. I. Sokol, L. V. Baikalova, V. S. Sergienko, et al., Zh. Neorg. Khim., 54, No. 6, 971–980 (2009).
M. G. Voronkov, É. A. Zel’bst, A. D. Vasiliev, et al., J. Struct. Chem., 52, No. 5 (2011).
M. G. Voronkov, É. A. Zel’bst, A. A. Kashaev, et al., Dokl. Akad. Nauk, 376, No. 2, 204–206 (2001).
M. G. Voronkov, É. A. Zel’bst, V. S. Fundamenskii, et al., Dokl. Akad. Nauk, 381, No. 3, 348–350 (2001).
M. G. Voronkov, É. A. Zel’bst, A. A. Kashaev, et al., Dokl. Akad. Nauk, 386, No. 1, 56–60 (2002).
M. G. Voronkov, É. A. Zel’bst, A. A. Kashaev, et al., Dokl. Akad. Nauk, 389, No. 4, 478–481 (2003).
M. G. Voronkov, É. A. Zel’bst, A. A. Kashaev, et al., Dokl. Akad. Nauk, 391, No. 6, 772–776 (2003).
M. G. Voronkov, É. A. Zel’bst, A. A. Kashaev, et al., Dokl. Akad. Nauk, 397, No. 1, 57–60 (2004).
M. G. Voronkov, V. S. Fundamenskii, É. A. Zel’bst, et al., Dokl. Akad. Nauk, 401, No. 1, 41–43 (2005).
M. G. Voronkov, É. A. Zel’bst, V. S. Fundamenskii, et al., J. Struct. Chem., 46, No. 6, 1114–1117 (2005).
V. A. Chetverikova, V. A. Kogan, G. I. Zelchan, et al., Zh. Obshch. Khim., 40,Vyp. 6, 1282–1285 (1970).
V. A. Chetverikova, A. S. Grishchenko, V. A Kogan, et al., Zh. Obshch. Khim., 40,Vyp. 6, 1285–1288 (1970).
M. C. Burla, R. Caliandro, B. Carrozzini, et al., J. Appl. Cryst., 37, No. 2, 258–264 (2004).
Cambridge Structural Database System, Version 5.29 (2007)
U. P. Chaudhuri, L. R. Whiteaker, A. Mondal, et. al., Inorg. Chem. Acta, 360, No. 11, 3610–3618 (2007).
Sun-Jun Peng, Cong-Shan Zhou, and Tao Yang., Acta Crystallogr. (E), 62, m1147–m1149 (2006).
Xiao Han, Zhong-Lu You, Yong-Ting Xu, and Xiao-Min Wang., J. Chem. Cryst., 36, No. 11, 743–746 (2006).
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Original Russian Text Copyright © 2011 by M. G. Voronkov, É. A. Zel’bst, V. S. Fundamenskii, V. A. Bruskov, A. A. Kashaev, A. S. Soldatenko, Yu. I. Bolgova, and O. M. Trofimova
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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 4, pp. 847–849, July–August, 2011.
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Voronkov, M.G., Zel’bst, É.A., Fundamenskii, V.S. et al. Unusual crystal and molecular structure of the 1-(1-silatranylmethyl)-3,5-dimethylpyrazole complex with zinc dichloride. J Struct Chem 52, 828–830 (2011). https://doi.org/10.1134/S0022476611040305
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DOI: https://doi.org/10.1134/S0022476611040305