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Crystal structure of C17H20FN3O 2+3 ·CuBr 2−4 ·H2O

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Abstract

A new compound C17H20FN3O 2+3 ·CuBr 2−4 ·H2O is synthesized in the crystal form, where C17H18FN3O3 (CfH, ciprofloxacin) is 4-oxo-7-(1-piperazinyl)-6-fluoro-1-cyclopropyl-1,4-dihydroquinoline-3-carboxylic acid. Crystallographic data of ciprofloxacinium tetrabromocuprate(II) monohydrate, C17H22Br4CuFN3O4: a = 8.214(1) Å, b = 10.781(2) Å, c = 13.703(2) Å, α = 85.144(2)°, β = 79.119(2)°, γ = 84.018(2)°, V = 1182.5(4) Å3, P \(\bar 1\) space group, Z = 2. Supramolecular architecture of the crystal differs from that established for C17H20FN3O 2+3 ·CuCl 2−4 ·H2O by the absence of π-π interactions of the aromatic rings of CfH 2+3 ions and also the structural motifs formed by intermolecular hydrogen bonds.

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  1. Siberian Federal University, Krasnoyarsk, Russia

    A. D. Vasiliev & N. N. Golovnev

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  1. A. D. Vasiliev
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  2. N. N. Golovnev
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Correspondence to N. N. Golovnev.

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Original Russian Text Copyright © 2011 by A. D. Vasiliev and N. N. Golovnev

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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 4, pp. 829–832, July–August, 2011.

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Vasiliev, A.D., Golovnev, N.N. Crystal structure of C17H20FN3O 2+3 ·CuBr 2−4 ·H2O. J Struct Chem 52, 809–812 (2011). https://doi.org/10.1134/S0022476611040251

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  • DOI: https://doi.org/10.1134/S0022476611040251

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