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Phase Formation in the V2O5–AlN System

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Inorganic Materials Aims and scope

An Erratum to this article was published on 01 September 2023

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Abstract—

Interactions in the V2O5–AlN system have been studied using chemical analysis, X-ray diffraction, and thermal analysis in combination with mass spectrometry. The results demonstrate that heating mixtures with AlN/V2O5 molar ratios ≥2.33 to above 1100°C leads to the formation of the vanadium nitrides V2N, VN0.81, and VN among condensed reaction products. No formation of solid solutions of aluminum in vanadium or vanadium aluminides during heating has been detected in the temperature range studied. Chemical interaction of V2O5 with AlN meets Baikov’s transformation sequence principle: V2O5 → VO2 → V4O7 → V3O5 → V2O3 → VO → V.

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ACKNOWLEDGMENTS

In this study, we used equipment at the Ural-M Shared Research Facilities Center.

Funding

This work was supported by the Russian Federation Ministry of Science and Higher Education through the state research target for the Institute of Metallurgy, Ural Branch, Russian Academy of Sciences; state registration no. 122020100404-2.

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Authors and Affiliations

  1. Institute of Metallurgy, Ural Branch, Russian Academy of Sciences, 620016, Yekaterinburg, Russia

    A. V. Larionov, R. I. Gulyaeva & E. A. Nifontova

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  1. A. V. Larionov
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  2. R. I. Gulyaeva
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  3. E. A. Nifontova
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Correspondence to A. V. Larionov.

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Translated by O. Tsarev

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Larionov, A.V., Gulyaeva, R.I. & Nifontova, E.A. Phase Formation in the V2O5–AlN System. Inorg Mater 59, 59–68 (2023). https://doi.org/10.1134/S0020168523010144

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