Abstract—
Barium strontium niobate films have been grown on MgO(001) substrates by single-step rf cathode sputtering of a ceramic target with the stoichiometric composition Sr0.5Ba0.5Nb2O6 in an oxygen atmosphere under various conditions (at different substrate biases). It has been shown that, depending on its polarity, the substrate bias either increases or reduces the flux of structure-forming elements to the substrate and, as a consequence, changes the growth rate, without impairing the surface morphology or surface perfection of the film or producing impurity phases. The mechanisms underlying the observed general relationships are discussed.
Similar content being viewed by others
REFERENCES
Mukhortov, V.M. and Yuzyuk, Yu.I., Geterostruktury na osnove nanorazmernykh segnetoelektricheskikh plenok: poluchenie, svoistva i primenenie (Heterostructures Based on Ferroelectric Nanofilms: Fabrication, Properties, and Application), Rostov-on-Don: YuNTs Ross. Akad. Nauk, 2008.
Sando, D., Yang, Y., Paillard, C., Dkhil, B., Bellaiche, L., and Nagarajan, V., Epitaxial ferroelectric oxide thin films for optical applications, Appl. Phys. Rev., 2018, vol. 5, paper 041108.https://doi.org/10.1063/1.5046559
Physics of Ferroelectrics: A Modern Perspective, Rabe, K.M., Ahn, Ch.H., and Triscon, J.-M., Eds., Berlin: Springer, 2007.
Mukhortov, V.M., Golovko, Yu.I., Tolmachev, G.N., and Mashchenko, A.I., Heteroepitaxial growth of complex-oxide films from a self-organized system formed in a gas-discharge plasma, Tech. Phys., 1999, vol. 44, no. 6, pp. 1477–1480.https://doi.org/10.1134/1.1259552
Berlin, E.V. and Seidman, L.A., Ionno-plazmennye protsessy v tonkoplenochnoi tekhnologii (Ion-Plasma Processes in Thin Film Technology), Moscow: Tekhnosfera, 2010.
Guruvenketa, S., Ghatak, J., Satyam, P.V., and Rao, M.G., Characterization of bias magnetron-sputtered silicon nitride films, Thin Solid Films, 2005, vol. 478, pp. 256–260.https://doi.org/10.1016/j.tsf.2004.10.031
Audronis, M., Matthews, A., and Leyland, A., Pulsed-bias magnetron sputtering of non-conductive chromia films at low substrate temperature, J. Phys. D: Appl. Phys., 2008, vol. 41, paper 035309.https://doi.org/10.1088/0022-3727/41/3/035309
Mukhortov, V.M., Golovko, Yu.I., and Tolmachev, G.N., Preparation of single-crystal mixed oxide nanofilms via atom–cluster–crystal three-dimensional ordering, Vestn. Yuzhn. Nauchn. Tsentra Ross. Akad. Nauk, 2006, vol. 2, no. 1, pp. 30–36.
Tolmachev, G.N., Kovtun, A.P., Zakharchenko, I.N., Aliev, I.M., Pavlenko, A.V., Reznichenko, L.A., and Verbenko, I.A., Synthesis, structure, and optical characteristics of barium–strontium niobate thin films, Phys. Solid State, 2015, vol. 57, no. 10, pp. 2106–2111.https://doi.org/10.1134/S1063783415100339
Pavlenko, A.V., Zakharchenko, I.N., Kudryavtsev, Yu.A., Kiseleva, L.I., and Alikhadzhiev, C.Kh., Structural characteristics of thin Sr0.5Ba0.5Nb2O6 films in the temperature range 20–500 °C, Inorg. Mater., 2020, vol. 56, no. 11, pp. 1188–1192.https://doi.org/10.1134/S0020168520100118
Stokes, A.R. and Wilson, A.J.C., The diffraction of X rays by distorted crystal aggregates-I, Proc. Phys. Soc., 1944, vol. 56, pp. 174–181.https://doi.org/10.1088/0959-5309/56/3/303
Volmer, M. and Weber, A., Nucleus formation in supersaturated systems, Z. Phys. Chem., 1926, vol. 119, pp. 277–301.https://doi.org/10.1515/zpch-1926-11927
Chernaya, T.S., Maksimov, B.A., Volk, T.R., Ivleva, L.I., and Simonov, V.I., Atomic structure of Sr0.75Ba0.25Nb2O6 single crystal and composition–structure–property relation in (Sr,Ba)Nb2O6 solid solutions, Phys. Solid State, 2000, vol. 42, no. 9, pp. L1716–1721.https://doi.org/10.1134/1.1309457
ACKNOWLEDGMENTS
In this study, we used equipment at the Electromagnetic, Electromechanical, and Thermal Properties of Solids Shared Research Facilities Center, Research Institute of Physics, Southern Federal University, and at the Joint Scientific and Technological Equipment Center (Shared Research Facilities Center), Southern Scientific Center, Russian Academy of Sciences (research, development, and evaluation).
Funding
This work was supported by the Russian Federation Ministry of Science and Higher Education (state research target for the Southern Scientific Center, Russian Academy of Sciences, state registration no. 01201354247).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Tsarev
Rights and permissions
About this article
Cite this article
Pavlenko, A.V., Zinchenko, S.P., Stryukov, D.V. et al. Effect of Substrate Bias on the Crystal Structure and Morphology of Barium Strontium Niobate Films Grown by RF Cathode Sputtering. Inorg Mater 57, 377–382 (2021). https://doi.org/10.1134/S0020168521040117
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168521040117