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Synthesis and Thermoluminescence Properties of PbCd2 –xMnxB6O12 Solid Solutions

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Abstract—

Powders of the double borate PbCd2B6O12 and PbCd2 –xMnxB6O12 solid solutions have been prepared by solid-state reactions and the crystallographic characteristics of the synthesized phases have been determined (sp. gr. P21/n). Using differential scanning calorimetry and X-ray diffraction, the PbCd2B6O12 compound has been shown to melt incongruently at 734°C. The effect of activator ion concentration on the thermoluminescence intensity in phases of variable composition at temperatures in the range 25–400°C has been studied for the first time. The sample containing 5 mol % Mn2+ ions has been shown to offer the highest luminescence brightness in the visible spectral region.

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  1. Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, ul. Sakh’yanovoi 6, 670047, Ulan-Ude, Buryat Republic, Russia

    T. N. Khamaganova

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Translated by O. Tsarev

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Khamaganova, T.N. Synthesis and Thermoluminescence Properties of PbCd2 –xMnxB6O12 Solid Solutions. Inorg Mater 55, 290–294 (2019). https://doi.org/10.1134/S0020168519030117

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  • DOI: https://doi.org/10.1134/S0020168519030117

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