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Synthesis and Thermoluminescence of Borates Pb1–xEuxCd2B6O12

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The thermoluminescent properties of PbCd2B6O12 crystal phosphors doped with Eu3+ ions and exposed to β-ray irradiation are investigated. Polycrystalline samples of the initial matrix and solid solutions based on it were synthesized by solid-phase reactions and characterized by X-ray phase analysis, IR spectroscopy, and differential scanning calorimetry. The dependences of the thermoluminescence intensity on the concentration of the activator ions in the temperature range 25–400°C were obtained. The optimal composition of the phosphor Pb1–xCd2B6O12 :хEu3+ (x = 0.05), which provides the maximum luminescence brightness, was determined.

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REFERENCES

  1. Daniels, F., Boyd, C.A., and Saunders, D.F., Science, 1953, vol. 117, pp. 343–349. https://doi.org/10.1126/science.117.3040.343

    Article  CAS  PubMed  Google Scholar 

  2. Wagner, G.A., Age Determination of Young Rocks and Artifacts: Physical and Chemical Clocks in Quaternary Geology and Archaeology (Natural Science in Archaeology), Berlin: Springer, 1998.

    Book  Google Scholar 

  3. Bos, A.J.J., Radiat. Meas., 2007, vol. 41, pp. 45–56. https://doi.org/10.1016/j.radmeas.2007.01.003

    Article  CAS  Google Scholar 

  4. Doull, B.A., Oliveira, L.C., Wang, D.Y., Milliken, E.D., and Yukihara, E.G., J. Lumin., 2014, vol. 146, pp. 408–417. https://doi.org/10.1016/j.jlumin.2013.10.022

    Article  CAS  Google Scholar 

  5. Furetta, C., Kitis, G., Weng, P.S., and Chu, T.C., Nucl. Instr. Meth. A, 1999, vol. 420, no. 3, pp. 441–445. https://doi.org/10.1016/S0969-8043(99)00124-4

    Article  CAS  Google Scholar 

  6. Senguttuvan, N., Ishii, M., Shimoyama, M., Kobayashi, M., Tsutsui, N., Nike, M., Dusek, M., Shimizu, H.M., Oku, T., Adachi, T., Sakai, K., and Suzuki, J., Nucl. Instr. Meth. A, 2002, vol. 486, nos. 1–2, pp. 264–267. https://doi.org/10.1016/S0168-9002(02)00714-3

    Article  CAS  Google Scholar 

  7. Manam, J. and Sharma, S.K., Semicond. Physics, Quant. Electr. & Optoelectr., 2003, vol. 6, pp. 465–470.

    Article  CAS  Google Scholar 

  8. Adamiv, V.T., Antonyak, O.T., Burak, Ya.V., and Teslyuk, I.M., J. Lumin., 2008, vol. 128, pp. 549–552. https://doi.org/10.1016/j.jlumin.2007.10.006

    Article  CAS  Google Scholar 

  9. Simura, R., Kawai , S., Sugiyama, K., Yanagida, T., Sugawara, T., Shishido, T., and Yoshikawa, A., J. Cryst. Growth, 2013, vol. 362, pp. 296–299. https://doi.org/10.1016/j.jcrysgro.2011.11.089

    Article  CAS  Google Scholar 

  10. Cai, G.M., Yang, N., Liu, H.X., Zhang, Y.Q., and Si, J.Y., J. Lumin., 2017, vol. 187, pp. 211–220. https://doi.org/10.1016/j.jlumin.2017.03.017

    Article  CAS  Google Scholar 

  11. Pir, P.V., Shabanov, E.V., and Dotsenko, V.P., Vestn. Odessk. Nats. Univ., 2005, vol. 10, no. 1, pp. 21–27.

    Google Scholar 

  12. Hanuza, J., Maczka, M., Lorenc, J., Kaminskii, A.A., Becker, P., and Bohaty, L., J. Raman Spectrosc., 2008, vol. 39, pp. 409–414. https://doi.org/10.1002/jrs.1840

    Article  CAS  Google Scholar 

  13. Shmurak, S.Z., Kedrov, V.V., Kiselev, A.P., Fursova, T.N., and Shmyt’ko, I.M., Phys. Solid State, 2015, vol. 57, no. 8, pp. 1588–1600. https://doi.org/10.1134/S1063783415080326 

    Article  CAS  Google Scholar 

  14. Khamaganova, T.N., Khumaeva, T.G., Subanakov, A.K., and Perevalov, A.V., Inorg. Mater., 2017, vol. 53, no. 1, pp. 81–85. https://doi.org/10.1134/S0020168517010101

    Article  CAS  Google Scholar 

  15. Hao, Y.-C., Xu, X., Kong, F., Song, J.-L., and Mao, J.-G., CrystEngComm., 2014, vol. 16, pp. 7689–7695. https://doi.org/10.1039/c4ce00777h

    Article  CAS  Google Scholar 

  16. RF Patent 2651255 (Publ 2018).

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Funding

The work was carried out within the framework of the state assignment of the Baikal Institute of Nature Management of SB RAS in accordance with the Program of Fundamental Scientific Research of the State Academies of Sciences for 2017-2020 in the direction V.45, project no. V.45.1. (number of state registration in the EGISU R&D system АААА-А17-117021310256-9).

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Authors and Affiliations

  1. Baikal Institute of Nature Management, Siberian Branch of Russian Academy of Sciences, 670047, Ulan-Ude, Russia

    T. N. Khamaganova

  2. Geological Institute, Siberian Branch of Russian Academy of Sciences, 670047, Ulan-Ude, Russia

    T. G. Khumaeva & A. V. Perevalov

Authors
  1. T. N. Khamaganova
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  2. T. G. Khumaeva
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  3. A. V. Perevalov
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Corresponding author

Correspondence to T. N. Khamaganova.

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Khamaganova, T.N., Khumaeva, T.G. & Perevalov, A.V. Synthesis and Thermoluminescence of Borates Pb1–xEuxCd2B6O12. Russ J Appl Chem 93, 1387–1391 (2020). https://doi.org/10.1134/S1070427220090116

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