Abstract
A NiV2O6–25 wt % V2O5 molten-oxide material has been prepared and characterized, and its transport properties (electrical conductivity, oxygen ion transport number, and oxygen permeability) have been studied in the temperature range 680–700°C. The results demonstrate that the molten-oxide membrane material obtained possesses high selective oxygen permeability (KO2 = (2.5–5.6) × 10–10 mol/(cm s) in the range 680–740°C and \(\frac{{{j_{{O_2}}}}}{{{j_{{N_2}}}}}\) ~ 1500) and can be used in separators for the preparation of extrapure oxygen from air.
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Sunarso, J., Baumann, S., Serra, J.M., Meulenberg, W.A., Liu, S., Lin, Y.S., and Diniz da Costa, J.C., Mixed ionic–electronic conducting (MIEC) ceramic–based membranes for oxygen separation, J. Membr. Sci., 2008, vol. 320, pp. 13–41.
Zeng, P., Chen, Z., Zhou, W., Gu, H., Shao, Z., and Liu, S., Re–evaluation of Ba0.5Sr0.5Co0.8Fe0.2O3–δ perovskite as oxygen semi–permeable membrane, J. Membr. Sci., 2007, vol. 291, pp. 148–156.
Teraoka, Y., Zhang, H.M., Furukawa, S., and Yamazoe, N., Oxygen permeation through perovskite–type oxides, Chem. Lett., 1985, no. 11, pp. 1743–1746.
Ullmann, H., Trofimenko, N., Tietz, F., Stover, D., and Ahmad–Khanlou, A., Correlation between thermal expansion and oxide ion transport in mixed conducting perovskite–type oxides for SOFC cathodes, Solid State Ionics, 2000, vol. 138, pp. 79–90.
Liu, Y., Zhu, X., Li, M., Liu, H., Cong, Y., and Yang, W., Stabilization of low–temperature degradation in mixed ionic and electronic conducting perovskite oxygen permeation membranes, Angew. Chem., Int. Ed., 2013, vol. 52, pp. 3232–3236.
Zhu, X. and Yang, W., Mixed Conducting Ceramic Membranes: Fundamentals, Materials and Applications, Berlin: Springer, 2017.
Belousov, V.V. and Fedorov, S.V., Accelerated mass transfer involving the liquid phase in solids, Russ. Chem. Rev., 2012, vol. 81, pp. 44–64.
Belousov, V.V., Electrical and mass transport processes in molten oxide membranes, Ionics, 2016, vol. 22, pp. 451–469.
Belousov, V.V., Innovative oxide materials for electrochemical energy conversion and oxygen separation, Russ. Chem. Rev., 2017, vol. 86, pp. 934–950.
Belousov, V.V., Next–generation electrochemical energy materials for intermediate temperature molten oxide fuel cells and ion transport molten oxide membranes, Acc. Chem. Res., 2017, vol. 50, pp. 273–280.
Belousov, V.V., Kulbakin, I.V., Fedorov, S.V., and Klimashin, A.A., Novel molten oxide membrane for ultrahigh purity oxygen separation from air, ACS Appl. Mater. Interfaces, 2016, vol. 34, pp. 22 324–22 329.
Klimashin, A.A. and Belousov, V.V., Oxygen ion transport in molten oxide membranes for air separation and energy conversion, J. Electrochem. Soc., 2017, vol. 164, pp. H5353–H5356.
Belousov, V.V., Fedorov, S.V., and Vorobiev, A.V., The oxygen permeation of solid/melt composite BiVO4–10 wt % V2O5 membrane, J. Electrochem. Soc., 2011, vol. 158, pp. B601–B604.
Kul’bakin, I.V., Fedorov, S.V., Vorob’ev, A.V., and Belousov, V.V., Transport properties of ZrV2O7–V2O5 composites with liquid–channel grain boundary structure, Russ. J. Electrochem., 2013, vol. 49, pp. 878–882.
Vinke, I.C., Diepgrond, J., Boukamp, B.A., de Vries, K.J., and Burggraaf, A.J., Bulk and electrochemical properties of BiVO4, Solid State Ionics, 1992, vol. 57, pp. 83–89.
Buchanan, R.C. and Wolter, G.W., Properties of hotpressed zirconium pyrovanadate ceramics, J. Electrochem. Soc., 1983, vol. 130, pp. 1905–1910.
Palanna, O.G., Shashi, Mohan A.L., and Biswas, A.B., Electrical and magnetic properties of 3d–transition metal vanadates, Proc. Indian Acad. Sci. A, 1977, vol. 86, pp. 455–463.
Kozhevnikov, V.L., Kotik, M.L., Cheshnitskii, S.M., Zolotukhina, L.V., Surat, L.L., Sirina, T.P., and Fotiev, A.A., Phase relationships in the NiO–V2O5 system, Russ. J. Inorg. Chem., 1987, vol. 32, pp. 1358–1360.
Fedorov, S.V., Belousov, V.V., and Vorobiev, A.V., Transport properties of BiVO4–V2O5 liquid–channel grain–boundary structures, J. Electrochem. Soc., 2008, vol. 155, pp. F241–F244.
Ruiz–Trejo, E., Boldrin, P., Lubin, A., Tariq, F., Fearn, S., Chater, R., Cook, S.N., Atkinson, A., Gruar, R.I., Tighe, C.J., Darr, J., and Brandon, N.P., Novel composite cermet for low–metal–content oxygen separation membranes, Chem. Mater., 2014, vol. 26, pp. 3887–3895.
Ten Elshof, J.E., Nguyen, N.Q., den Otter, M.W., and Bouwmeester, H.J.M., Oxygen permeation properties of dense Bi1.5Er0.5O3–Ag cermet membranes, J. Electrochem. Soc., 1997, vol. 144, pp. 4361–4366.
Kharton, V.V., Kovalevsky, A.V., Viskup, A.P., Figueiredo, F.M., Yaremchenko, A.A., Naumovich, E.N., and Marques, F.M.B., Oxygen permeability and Faradaic efficiency of Ce0.8Gd0.2O2–δ–La0.7Sr0.3MnO3–δ composites, J. Eur. Ceram. Soc., 2001, vol. 21, pp. 1763–1767.
Allersma, T., Hakim, R., Kennedy, T.N., and Mackenzie J.D. Structure and physical properties of solid and liquid vanadium pentoxide, J. Chem. Phys., 1967, vol. 46, pp. 154–160.
Pantony, D.A. and Vasu, K.I., Studies in the corrosion of metals under melts–II: relevant physico–chemical properties of molten vanadium pentoxide, J. Inorg. Nucl. Chem., 1968, vol. 30, pp. 433–455.
Kerby, R.C. and Wilson, J.R., Electrical conduction properties of liquid vanadates. I. Vanadium pentoxide, Can. J. Chem., 1972, vol. 50, pp. 2865–2870.
Wagner, C., Beitrag zur Theorie des Anlaufvorgangs, Z. Phys. Chem., 1933, vol. 21, pp. 25–41.
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Original Russian Text © I.V. Kulbakin, A.A. Solovieva, S.V. Fedorov, V.V. Artemov, V.V. Belousov, 2018, published in Neorganicheskie Materialy, 2018, Vol. 54, No. 10, pp. 1116–1122.
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Kulbakin, I.V., Solovieva, A.A., Fedorov, S.V. et al. Highly Oxygen-Permeable NiV2O6–25 wt % V2O5 Molten-Oxide Membrane Material. Inorg Mater 54, 1055–1061 (2018). https://doi.org/10.1134/S0020168518100114
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DOI: https://doi.org/10.1134/S0020168518100114