Abstract
We have studied the crystallization conditions of single-phase nanopowders of solid solutions between mixed oxides based on titanium(IV), zirconium(IV), and divalent metals (barium, strontium, and lead). Our results demonstrate that hydrous ammonium-containing oxohydroxo precursors to titanium(IV) and zirconium(IV) have considerable potential for use in the synthesis of such materials.
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Venigalla, S., Clancy, D.J., Miller, D.V., et al., Hydrothermal BaTiO3-based aqueous slurries, Am. Ceram. Soc. Bull., 1999, vol. 78, no. 10, pp. 51–54.
Balkevich, V.L., Tekhnicheskaya keramika (Technical Ceramics), Moscow: Izd. Literatury po Stroitel’stvu, 1968.
Vereshchagin, V.I., Pletnev, P.M., Surzhikov, A.P., Fedorov, V.E., and Rogov, I.I., Funktsional’naya keramika (Functional Ceramics), Vereshchagin, V.I., Ed., Novosibirsk: Inst. Neorg. Khim. Sib. Otd. Ross. Akad. Nauk, 2004.
Rotenberg, B.A., Keramicheskie kondensatornye dielektriki (Ceramic Capacitor Dielectrics), St. Petersburg: Tipografiya OAO NII Girikond, 2000.
Antonov, N.N., Buzin, I.M., Vendik, O.G., et al., Segnetoelektriki v tekhnike SVCh (Ferroelectrics in Microwave Technologies), Vendik, O.G., Ed., Moscow: Sovetskoe Radio, 1979.
Rotenberg, B.A., Dorokhova, M.P., Ditenkova, T.A., and Ryabinina, S.P., New ferroelectric ceramic materials for capacitors, Elektron. Tekh., Ser. Radiodetali Radiokomponenty, 1986, no. 2 (36), pp. 3–8.
Lokshin, E.P., Ivanenko, V.I., Gromov, O.G., and Kalinnikov, V.T., Synthesis of mixed oxides of group IV and V rare elements (a review), Steklo Keram., 2005, no. 8, pp. 14–18.
Okazaki, K., Tekhnologiya keramicheskikh dielektrikov (Ceramic Engineering for Dielectrics), Moscow: Energiya, 1976.
Limar’, T.F., Borshch, A.N., Slatinskaya, I.G., et al., Chemical approaches to the preparation of advanced ceramic capacitor materials, Obz. Inf. NIITEKhIM. Obshcheotrasl. Vopr., 1988, no. 10.
Flashen, S.S., Aqueous synthesis of barium titanate, J. Am. Chem. Soc., 1955, vol. 77, no. 12, pp. 6194–6198.
Diaz-Guemes, M.I., Gonzales Carreno, T., Serna, C.J., and Palacios, J.M., Mechanism of formation of MTiO3 (M–Sr or Ba) by the gel method, J. Mater. Sci., 1989, vol. 24, no. 3, pp. 1011–1014.
Chaput, F. and Boilot, J.P., Chemical processing of (Ba,Sr)(Ti,Zr)O3 perovskite ceramics, J. Mater. Sci. Lett., 1987, vol. 6, no. 9, pp. 1110–1112.
Chaput, F. and Boilot, J.P., Alkoxide–hydroxide route to synthesize BaTiO3-based powders, J. Am. Ceram. Soc., 1990, vol. 73, no. 4, pp. 942–948.
Golubko, N.V., Yanovskaya, M.I., and Romm, I.P., A Thermochemical study of hydrolysis of titanium butoxide, Russ. J. Phys. Chem. A, 1997, vol. 71, no. 10, pp. 1569–1571.
Golubko, N.V., Yanovskaya, M.I., Prutchenko, S.G., and Obolonkova, E.S., Hydrolysis of Ti(OBu)4, Inorg. Mater., 1998, vol. 3, no. 9, pp. 932–938.
Golubko, N.V., Yanovskaya, M.I., Golubko, L.A., Kovsman, E.P., Listoshina, M.B., and Rotenberg, B.A., Preparation of barium titanate and related materials by the alkoxide–hydroxide method, Inorg. Mater., 1999, vol. 35, no. 4, pp. 387–982.
Ivanenko, V.I., Lokshin, E.P., Gromov, O.G., and Kalinnikov, V.T., Sintez segnetoelektricheskikh i lyuminestsentnykh slozhnykh oksidov redkikh elementov (Synthesis of Ferroelectric and Luminescent Rare-Element Mixed Oxides), Apatity: Kol’skii Nauchnyi Tsentr Ross. Akad. Nauk, 2009.
Ivanenko, V.I., Lokshin, E.P., Yakubovich, E.N., Vladimirova, S.V., and Kalinnikov, V.T., Synthesis of divalent metal metatitanate nanopowders, Perspekt. Mater., 2007, no. 4, pp. 73–82.
Kalinnikov, V.T., Lokshin, E.P., Ivanenko, V.I., Gromov, O.G., Udalova, I.A., Kuz’min, A.P., and Kunshina, G.B., Preparation of ultrafine powders and epitaxial nanofilms group IV and V rare-element oxide and orthophosphate compounds, Perspekt. Mater., 2003, no. 3, pp. 73–79.
Smazhevskaya, E.G. and Fel’dman, N.B., P’ezoelektricheskaya keramika (Piezoelectric Ceramics), Moscow: Sovetskoe Radio, 1971.
Glozman, I.A., P’ezokeramika (Piezoelectric Ceramics), Moscow: Energiya, 1967.
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Original Russian Text © V.I. Ivanenko, E.N. Yakubovich, S.V. Vladimirova, E.P. Lokshin, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 9, pp. 995–1002.
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Ivanenko, V.I., Yakubovich, E.N., Vladimirova, S.V. et al. Synthesis of powders of solid solutions between barium, strontium, and lead titanates and zirconates. Inorg Mater 51, 916–922 (2015). https://doi.org/10.1134/S0020168515090095
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DOI: https://doi.org/10.1134/S0020168515090095