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Synthesis, characterization and thermal expansion of the zinc-containing phosphates with the mineral-like framework structures

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Abstract

The new phosphates ZnxMg0.5+xE2−x(PO4)3 (E = Ti, Zr) were synthesized by the sol–gel method followed by heat treatment. Obtained samples were characterized with X-ray, IR, DTA and microprobe electron analyses. The ZnxMg0.5+xTi2−x(PO4)3 solid solution (0 ≤ x ≤ 0.5, kosnarite-type, sp. gr. R\(\bar{3}\)) is stable up to 1323 K. The ZnxMg0.5+xZr2−x(PO4)3 solid solution (0 ≤ x ≤ 0.5, Sc2(WO4)3-type, sp. gr. P21/n) is thermally unstable above 1273 K. The thermal expansion of ZnxMg0.5+xE2−x(PO4)3 solid solutions was studied in the temperature range 298–1073 K. The magnitudes of average volume thermal expansion coefficients vary from 1 × 10−5 to 5 × 10−6 K−1. The composition regulation of these medium- and high-expanding materials allows you to change the characteristics of thermal expansion in the required direction.

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Acknowledgements

The present work was performed at the Lobachevsky State University of Nizhni Novgorod with the financial support of the Russian Foundation for Basic Research (Project No. 18-29-12063).

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Authors and Affiliations

  1. National Research Lobachevsky State University, Nizhny Novgorod, Russia

    V. I. Pet’kov & D. A. Lavrenov

  2. Moscow Institute of Steel and Alloys (National University of Science and Technology), Moscow, Russia

    A. M. Kovalsky

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  1. V. I. Pet’kov
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  2. D. A. Lavrenov
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  3. A. M. Kovalsky
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Correspondence to V. I. Pet’kov.

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Pet’kov, V.I., Lavrenov, D.A. & Kovalsky, A.M. Synthesis, characterization and thermal expansion of the zinc-containing phosphates with the mineral-like framework structures. J Therm Anal Calorim 139, 1791–1798 (2020). https://doi.org/10.1007/s10973-019-08624-8

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