Abstract
Silver sulfide (Ag2S) powders have been synthesized through chemical precipitation from aqueous solutions of silver nitrate, sodium sulfide, and sodium citrate or Trilon B as a complexing agent and stabilizer. The synthesized Ag2S powders have a monoclinic (sp. gr. P21/c) acanthite (α-Ag2S) structure. The colloidal stock solutions decanted from the synthesized precipitate have been shown to be stable for at least a year. The particle size of the silver sulfide in the colloidal solutions and precipitated powders has been evaluated by dynamic light scattering, X-ray diffraction, and BET measurements. The results demonstrate that, varying the relative reactant concentrations in the starting reaction mixture, one can precipitate Ag2S nanoparticles of tailored average size in the range from ≃ 500 to ≃20–30 nm. The size of Ag2S nanoparticles in the stable colloidal solutions obtained is 15–20 nm.
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Rempel, A.A., Nanotechnologies, properties, and applications of nanostructured materials, Usp. Khim., 2007, vol. 76, no. 5, pp. 474–500.
Rempel, A.A., Hybrid nanoparticles based on sulfides, oxides, and carbides, Izv. Akad. Nauk, Ser. Khim., 2013, no. 4, pp. 857–869.
Rempel, A. and Magerl, A., Non-periodicity in nanoparticles with close-packed structures, Acta Crystallogr., Sect. A: Fundam. Crystallogr., 2010, vol. 66, no. 4, pp. 479–483.
Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1967, p. 94.
Patnaik, P., Dean’s Analytical Chemistry Handbook, New York: McGraw-Hill, 2004, 2nd ed., Table 4.2.
Lee, P.C. and Meisel, D., Adsorption and surfaceenhanced Raman of dyes on silver and gold sols, J. Phys. Chem., 1982, vol. 86, no. 17, pp. 3391–3395.
X’Pert Plus Version 1.0. Program for Crystallography and Rietveld Analysis, Amsterdam: Koninklijke Philips Electronics, 1999.
Gusev, A.I. and Rempel, A.A., Nanocrystalline Materials, Cambridge: Cambridge International Science, 2004.
Gusev, A.I. and Kurlov, A.S., Particle (grain) size characterization of nanocrystalline materials, Metallofiz. Noveishie Tekhnol., 2008, vol. 30, no. 5, pp. 679–694.
Sadovnikov, S.I. and Gusev, A.I., Chemical deposition of nanocrystalline lead sulfide powders with controllable particle size, J. Alloys Compd., 2014, vol. 586, pp. 105–112.
Sadovnikov, S.I., Kuznetsova, Yu.V., and Rempel, A.A., Synthesis of a stable colloidal solution of PbS nanoparticles, Inorg. Mater., 2014, vol. 50, no. 10, pp. 969–975.
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Original Russian Text © S.I. Sadovnikov, A.A. Rempel, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 8, pp. 829–837.
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Sadovnikov, S.I., Rempel, A.A. Synthesis of nanocrystalline silver sulfide. Inorg Mater 51, 759–766 (2015). https://doi.org/10.1134/S0020168515070134
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DOI: https://doi.org/10.1134/S0020168515070134