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Preparation and properties of photocatalytic composites based on titanium(IV), copper(II), and sodium(I) oxides

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Abstract

We have established conditions for the preparation of multiphase composites based on titanium(IV) and copper(II) oxides in a wide composition range and examined correlations between the phase composition, texture, and preparation conditions of the composites. Some of them have a mesoporous structure, consist of nanoparticles, and exhibit photocatalytic activity under illumination in the visible range.

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References

  1. Fenezonov, V.B. and Parmon, V.N., Introduction to the physical chemistry of texturing of heterogeneous photocatalysts, in Promyshlennyi kataliz v lektsiyakh (Lectures on Industrial Catalysis), Moscow: ZAO Kalvis, 2005, part 1.

    Google Scholar 

  2. Sedneva, T.A., Lokshin, E.P., Kalinnikov, V.T., and Belikov, M.L., Photocatalytic activity of tungstenmodified titanium oxide, Dokl. Phys. Chem., 2012, vol. 443, no. 1, pp. 57–59.

    Article  CAS  Google Scholar 

  3. Sedneva, T.A., Lokshin, E.P., Belikov, M.L., and Belyaevskii, A.T., TiO2- and Nb2O5-based photocatalytic composites, Inorg. Mater., 2013, vol. 49, no. 4, pp. 382–389.

    Article  CAS  Google Scholar 

  4. Miwa Takuya, Kaneco Satoshi, Katsumata Hideyuki, Suzuki Tohru, Ohta Kiyohisa, Verma Suresh Chand, and Sugihara Kunihiro, Photocatalytic hydrogen production from aqueous methanol solution with CuO/Al2O3/TiO2 nanocomposite, Int. J. Hydrogen Energy, 2010, vol. 35, no. 13, pp. 6554–6560.

    Article  Google Scholar 

  5. Hiratani, M., Kadoshima, M., Hirano, T., Shimamoto, Y., Maisui, Y., Nabatame, T., Torii, K., and Kimura, S., Ultra-thin titanium oxide film with a rutile-type structure, Appl. Surf. Sci., vol. 207, nos. 1–4, pp. 13–19.

  6. Zywitzci, O., Modes, T., Suhm, H., Frach, P., Goedicke, K., and Glob, D., Structure and properties of crystalline titanium oxide layers deposited by reactive pulse magnetron sputtering, Surf. Coat. Technol., 2004, vols. 180–181, pp. 538–543.

    Article  Google Scholar 

  7. Justicia, I., Garcia, G., Baltison, G.A., Gerbasi, R., Ager, F., Guerra, M., Caixach, L., Pardo, J.A., Rivera, J., and Fiqueras, A., Photocatalytic in the visible range of sub-stoichiometric anatase films prepared by MOCVD, Electrochim. Acta, 2005, vol. 50, pp. 4606–4608.

    Google Scholar 

  8. Ovchinnikov, S.G., Gizhevskii, B.A., Sukhorukov, Yu.P., Ermakov, A.E., Uimin, M.A., Kozlov, E.A., Kotov, Yu.A., and Bagazeev, A.V., Specific features of the electronic structure and optical spectra of nanoparticles with strong electron correlations, Phys. Solid State, 2007, vol. 49, no. 6, pp. 1116–1120.

    Article  CAS  Google Scholar 

  9. Samsonov, G.V., Bulankova, T.G., and Burykina, A.L., Fiziko-khimicheskie svoistva okislov. Spravochnik (Physicochemical Properties of Oxides: A Handbook), Moscow: Metallurgiya, 1969.

    Google Scholar 

  10. Baldi, D., Bitossi, M., and Bartsanti, A., RF Patent 2 431 604, Byull. Izobret., 2011, no. 29.

    Google Scholar 

  11. Shutilov, A.A., Zenkovets, G.A., Tsybulya, S.V., Gavrilov, V.Yu., and Kryukova, G.N., Effect of the microstructure of the supported catalysts CuO/TiO2 and CuO/(CeO2-TiO2) on their catalytic properties in carbon monoxide oxidation, Kinet. Catal., 2012, vol. 53, no. 3, pp. 409–418.

    Article  CAS  Google Scholar 

  12. Surkin, R.R., Zhimalov, A.B., Bondareva, L.N., Gorina, I.N., Gerancheva, O.E., and Polkan, G., RF Patent 2434819, Byull. Izobret., 2011, no. 33.

    Google Scholar 

  13. Bessekhouad, Y., Robert, D., and Weber, J.-V., Photocatalytic activity of Cu2O/TiO2, Bi2O3/TiO2 and ZnMn2O4/TiO2 heterojunctions, Catal. Today, 2005, vol. 101, nos. 3–4, pp. 315–321.

    Article  CAS  Google Scholar 

  14. Sedneva, T.A., Lokshin, E.P., Belikov, M.L., and Belyaevskii, A.T., Structure and morphology of ironmodified titania powders, Inorg. Mater., 2011, vol. 47, no. 11, pp. 1205–1213.

    Article  CAS  Google Scholar 

  15. Ivanova, V.P., Kasatov, B.K., Krasavina, T.N., and Rozinova, E.L., Termicheskii analiz mineralov i gornykh porod (Thermal Analysis of Minerals and Rocks), Leningrad: Nedra, 1974, pp. 47–118.

    Google Scholar 

  16. Gregg, S.J. and Sing, K.S.W., Adsorption, Surface Area, and Porosity, New York: Academic, 1982.

    Google Scholar 

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Correspondence to T. A. Sedneva.

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Original Russian Text © T.A. Sedneva, E.P. Lokshin, M.L. Belikov, A.T. Belyaevskii, 2014, published in Neorganicheskie Materialy, 2014, Vol. 50, No. 11, pp. 1195–1204.

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Sedneva, T.A., Lokshin, E.P., Belikov, M.L. et al. Preparation and properties of photocatalytic composites based on titanium(IV), copper(II), and sodium(I) oxides. Inorg Mater 50, 1104–1113 (2014). https://doi.org/10.1134/S0020168514110168

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  • DOI: https://doi.org/10.1134/S0020168514110168

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