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Impurity tin atoms in glassy As x S1 − x and As x Se1 − x

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Abstract

119Sn Mössbauer emission spectroscopy data demonstrate that the impurity tin atoms resulting from the radioactive decay of the 119Sb isotope in the structure of glassy As x S1 − x and As x Se1 − x alloys reside on the arsenic site and act as two-electron amphoteric centers with a negative correlation energy: tetravalent six-coordinate tin acts as a singly ionized donor, and divalent three-coordinate tin, as a singly ionized acceptor.

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Authors and Affiliations

  1. Gertsen State Pedagogical University, nab. Moiki 48, St. Petersburg, 191186, Russia

    G. A. Bordovsky, A. V. Marchenko & P. P. Seregin

  2. Ulugbek National University of Uzbekistan, Vuzgorodok, Tashkent, 700095, Uzbekistan

    K. U. Bobokhuzhaev

Authors
  1. G. A. Bordovsky
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  2. A. V. Marchenko
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  3. P. P. Seregin
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  4. K. U. Bobokhuzhaev
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Corresponding author

Correspondence to P. P. Seregin.

Additional information

Original Russian Text © G.A. Bordovsky, A.V. Marchenko, P.P. Seregin, K.U. Bobokhuzhaev, 2014, published in Neorganicheskie Materialy, 2014, Vol. 50, No. 11, pp. 1254–1260.

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Bordovsky, G.A., Marchenko, A.V., Seregin, P.P. et al. Impurity tin atoms in glassy As x S1 − x and As x Se1 − x . Inorg Mater 50, 1162–1168 (2014). https://doi.org/10.1134/S0020168514110028

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  • DOI: https://doi.org/10.1134/S0020168514110028

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