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ICP-AES analysis of high-purity silicon

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Abstract

An ICP-AES procedure for analyzing high-purity silicon, which is implemented on up-to-date standard equipment and intended to determine 44 impurities with detection limits of n × 10−8n × 10−6 wt % in silicon, is described. The procedure is compared with ICP-AES procedures, conforming to GOST (State Standard) and published in the literature, in quantity of determined impurities and their detection limits.

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References

  1. Nashel’skii, A.Ya., and Pul’ner, E.O., Up-to-date state of silicon technique for solar energy, Vysokochist. Veshchestva, 1996, no. 1, pp. 102–111.

    Google Scholar 

  2. Zaidi, J.H., Qurcshi, I.H., Arif, M., and Fatima, I., Measurement of trace impurities in high purity materials, J. Radioanal. Nucl. Chem., 1995, vol. 191, no. 1, pp. 75–82.

    Article  CAS  Google Scholar 

  3. Glavin, G.G., Kormilitsyn, D.V., Yudochkin, N.M., and Ovchinnikov, S.V., Application of spark mass-spectrometry for control of semiconductor silicon production in Proc. XIII Conf. High-Purity Substances and Materials. Production, analysis, and application, Nizhnii Novgorod, 2007, pp. 120–121.

    Google Scholar 

  4. Karpov, Yu.A., Shchulepnikov, M.N., Kormilitsyn, D.V., and Firsov, V.I., Analytical Control of Semiconductor Silicon, Vysokochist. Veshchestva, 1991, no. 4, pp. 31–37.

    Google Scholar 

  5. GOST (State Standard) 26239.1-84: Silicon semiconductor, initial products for its obtaining and quartz. Method of determination of impurities, 1985.

  6. Ueng, R.I., Jiang, S.J., Wan, C.C., and Sahayam, A.S., Microwave assisted volatilization of silicon fluorides for the determination of trace impurities in high purity silicon powder and quartz by ICP-MS, Anal. Chim. Acta, 2005, vol. 536, pp. 295–299.

    Article  CAS  Google Scholar 

  7. Krasil’shchik, V.Z., Lyutina, L.G., Amosov, Yu.I., and Yudelevich, I.G., Application of atomic emission spectrometry with inductively coupled plasma in analysis of high-purity substances, Vysokochist. veshchestva, 1990, no. 4, pp. 48–59.

    Google Scholar 

  8. Shelpakova, I.R. and Saprykin, A.I., Analysis of high-purity solid substances by the ICP-AES and ICP-MS methods, Usp. Khim. 2005, vol. 74, no. 11, pp. 1106–1117.

    Article  Google Scholar 

  9. Rouchaud, J.C., Debove, L., Fedoroff, M., etc., Multielement characterization of silicon by nuclear activation and inductively coupled plasma emission-spectrometry, Analysis, 1987, vol. 15, no. 6, pp. 275–285.

    CAS  Google Scholar 

  10. Fujimoto, K. and Okano, T., Determination of trace amounts of impurities in high purity silicon and silicate materials by vapor-phase pressured decomposition, ICP-AES and ICP-MS, Bunseki Kagaku, 1993, vol. 42, no. 10, pp. T135–T142.

    Article  CAS  Google Scholar 

  11. Piryutko, M.M., Chemical reactions of silicon with hydrofluoric and nitric acids, Zavod. Lab., Diagn. Mater., 1963, vol. 29, no. 10, pp. 1179–1180.

    CAS  Google Scholar 

  12. Bock, R., Decomposition methods in analytical chemistry, Moscow: Khimiya, 1984.

    Google Scholar 

  13. Zil’bershtein, Kh.I., Legeza, S.S., and Semov, M.P., Chemical-spectral analysis of thin semiconductor silicon wafers, ZhAKh, 1973, vol. 28, no. 7, pp. 1323–1329.

    Google Scholar 

  14. Surikov, V.T., Acid dissolution of silicon and its compounds for analyzing by the mass-spectrometry method with inductively coupled plasma, Analitika i kontrol, 2008, vol. 12, nos. 3–4, pp. 93–100.

    Google Scholar 

  15. Kuznetsov, F.A. and Reznichenko, M.F., Carbon-free semiconductor silicon techniques, in Proc. VI Int. Conf on Actual problems of physics, science of materials, technology and diagnostics of silicon, nanometer structures and devices on its basis, Novosibirsk, 2009, p. 20.

    Google Scholar 

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Correspondence to A. V. Shaverina.

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Original Russian Text © A.V. Shaverina, A.R. Tsygankova, I.R. Shelpakova, A.I. Saprykin, 2012, published in Zavodskaya Laboratoriya. Diagnostika Materialov, 2012, Vol. 78, No. 4, pp. 9–13.

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Shaverina, A.V., Tsygankova, A.R., Shelpakova, I.R. et al. ICP-AES analysis of high-purity silicon. Inorg Mater 49, 1283–1287 (2013). https://doi.org/10.1134/S0020168513140082

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  • DOI: https://doi.org/10.1134/S0020168513140082

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