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High-pressure/high-temperature synthesis, crystal structure, and electrical properties of CaCu3 − x Fe x V4O12

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Abstract

A perovskite-like compound of composition CaCu3 − x Fe x V4O12 (x = 0.7−1.0) has been synthesized at high pressures (p = 5.0−8.0 GPa) and temperatures (t = 1000−1300°C). Its crystal structure has been determined by X-ray diffraction (sp. gr. \(Im\bar 3\), Z = 2, a = 7.3051(5) angles have been evaluated. The electrical conductivity of the high-pressure phase CaCu2FeV4O12 exhibits metallic behavior.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya ul. 91, Yekaterinburg, 620219, Russia

    N. I. Kadyrova, Yu. G. Zainulin & A. P. Tyutyunnik

  2. Ural State University, pr. Lenina 51, Yekaterinburg, 620083, Russia

    N. V. Mel’nikova & I. S. Ustinova

Authors
  1. N. I. Kadyrova
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  2. Yu. G. Zainulin
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  3. A. P. Tyutyunnik
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  4. N. V. Mel’nikova
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  5. I. S. Ustinova
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Correspondence to N. I. Kadyrova.

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Original Russian Text © N.I. Kadyrova, Yu.G. Zainulin, A.P. Tyutyunnik, N.V. Mel’nikova, I.S. Ustinova, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 12, pp. 1527–1532.

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Kadyrova, N.I., Zainulin, Y.G., Tyutyunnik, A.P. et al. High-pressure/high-temperature synthesis, crystal structure, and electrical properties of CaCu3 − x Fe x V4O12 . Inorg Mater 47, 1396–1401 (2011). https://doi.org/10.1134/S0020168511110070

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  • DOI: https://doi.org/10.1134/S0020168511110070

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