Abstract
We report the optical and electrical properties of a-Si:H and a-Si1 − x C x :H (x = 0.06, 0.17, 0.25,0.32) amorphous films produced by plasma deposition at constant hydrogen content. IR absorption data are used to evaluate the density of Si-H and C-H bonds and the hydrogen concentration in the films. The activation energy for conduction and the carrier mobility in the films are determined from the temperature dependence of their electrical conductivity.
Similar content being viewed by others
References
Amorphous Semiconductors Technologies and Devices, Hamakawa, Y., Ed., Amsterdam: North-Holland, 1983.
Tetelbaum, D.I., Ezhevskii, A.A., and Mikhailov, A.N., Extremal Dependence of the Concentration of Paramagnetic Centers Related to Dangling Bonds in Silicon on Ion-Irradiation Dose As Evidence of Nanostructuring, Fiz. Tekh. Poluprovodn. (S.-Peterburg), 2002, vol. 37, no. 11, pp. 1380–1382.
Afanas’ev, V.P., Gudovskikh, A.S., Nevedomskii, V.N., and Sazonov, A.P., Effect of Heat Treatment on the Structure and Properties of Films Produced by Cyclic Deposition, Fiz. Tekh. Poluprovodn. (S.-Peterburg), 2003, vol. 36, no. 2, pp. 238–243.
Golikova, O.A., Bogdanova, E.V., and Babakhodzhaev, U.S., Crystallization of Hydrogenated Amorphous Silicon Films Deposited under Various Conditions, Fiz. Tekh. Poluprovodn. (S.-Peterburg), 2002, vol. 36, no. 10, pp. 1259–1262.
Bakirov, M.A., Najafov, B.A., Mamedov, V.S., and Zeinalov, N.M., Electrical Properties of Amorphous Ge1 − x Si x Solid-Solution Films, Dokl. Akad. Nauk Az. SSR, 1989, vol. 14, no. 1, pp. 19–22.
Wen-Yaung Lee, X-Ray Photoelectron Spectroscopy and Electron Spectroscopy Studies of Glow Discharge Si1 − x Cx:H Films, J. Appl. Phys., 1980, vol. 51, no. 6, pp. 3365–3372.
Najafov, B.A. and Isakov, G.I., Growth and Doping of Si-Ge Amorphous Films, Al’ternativnaya Energ. Ekol., 2005, no. 4 (24), pp. 79–81.
Najafov, B.A., Single-Layer and Bilayer Solar Cells Based on Amorphous Films, ISJAEE, 2005, vol. 27, no. 7, pp. 62–64.
Najafov, B.A., Sbornik trudov mezhdunarodnoi konferentsii po amorfnym i mikrokristallicheskim poluprovodnikam (Proc. Int. Conf. on Amorphous and Microcrystalline Semiconductors), St. Petersburg: Politekhnicheskii Univ., 2006, pp. 293–294.
Connell, G.A.N. and Pawlik, I.R., Use of Hydrogenation in Structural and Electronic Studies of Gap States in Amorphous Germanium, Phys. Rev. B: Solid State, 1976, vol. 13, no. 2, pp. 787–804.
Hallohon, Y.R. and Beel, A., Techniques and Application of Plasma Chemistry, New York: Wiley, 1974.
Metaqqart, F.K., Plasma Chemistry in Electrical Discharges, Monograph 9: Topics in Inorganic Chemistry, Robinson, P.Z., Ed., New York: Elsevier, 1967.
Tauc, J., Grigorovici, R., et al., Optical Properties and Electronic Structure of Amorphous Germanium, J. Non-Cryst. Solids, 1966, vol. 15, no. 1, pp. 627–630.
Fang, C.J., Cruntz, K.J., Ley, L., and Cardona, M., The Hydrogen Content of a-Ge:H and a-Si:H As Determined by IR Spectroscopy, Gas Evolution and Nuclear Reaction Techniques, J. Non-Cryst. Solids, 1980, vol. 35, no. 1, pp. 255–259.
Mott, N. and Davis, E., Electronic Processes in Non-Crystalline Materials, Oxford: Oxford Univ. Press, 1979, vol. 2.
Isakov, G.I. and Najafov, B.A., Optical Properties of Amorphous Films with Different Hydrogen Concentrations, Zh. Prikl. Spektrosk., 2005, vol. 72, no. 3, pp. 374–376.
Brodsky, M.M., Cardona, M., and Cuomo, J.J., Infrared and Raman Spectra of the Silicon Prepared by Glow Discharge and Sputtering, Phys. Rev. B: Solid State, 1977, vol. 6, no. 8, pp. 3556–3581.
Najafov, B.A. Electrical Properties of Amorphous Solid-Solution Films, Fiz. Tekh. Poluprovodn. (S.-Peterburg), 2000, vol. 34, no. 11, pp. 1383–1385.
Lewis, A., Evidence for the Mott Model of Hopping Conduction in the Anneal Stable State of Amorphous Silicon, Phys. Rev. Lett., 1978, vol. 29, no. 23, pp. 1555–1558.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © B.A. Najafov, G.I. Isakov, 2010, published in Neorganicheskie Materialy, 2010, Vol. 46, No. 6, pp. 702–708.
Rights and permissions
About this article
Cite this article
Najafov, B.A., Isakov, G.I. Optical and electrical properties of amorphous Si1 − x C x :H films. Inorg Mater 46, 624–630 (2010). https://doi.org/10.1134/S0020168510060129
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168510060129