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Phase diagram of the Pb-NiSb system and properties of (NiSb)1 − x Pb x solid solutions

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Abstract

The phase diagram of the Pb-NiSb system is presented. The system is pseudobinary, with a limited series of NiSb-based solid solutions: ≃1 mol % Pb at 300 K. In the temperature range ≃520–670 K, the system contains un unstable compound, Ni3Pb2Sb3. At 1320 K, a monotectic transformation occurs (≃15–71 mol % NiSb). Electrical and thermal conductivity measurements reveal an additional contribution to the lattice thermal resistivity of the (NiSb)1 − x Pb x solid solutions and show that electrons and phonons in these materials are scattered elastically.

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Authors and Affiliations

  1. Azerbaijani Technical University, pr. Javida 25, Baku, AZ1073, Azerbaijan

    Ch. I. Abilov & M. F. Agaeva

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  1. Ch. I. Abilov
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  2. M. F. Agaeva
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Correspondence to Ch. I. Abilov.

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Original Russian Text © Ch.I. Abilov, M.F. Agaeva, 2010, published in Neorganicheskie Materialy, 2010, Vol. 46, No. 2, pp. 141–144.

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Abilov, C.I., Agaeva, M.F. Phase diagram of the Pb-NiSb system and properties of (NiSb)1 − x Pb x solid solutions. Inorg Mater 46, 104–107 (2010). https://doi.org/10.1134/S0020168510020020

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  • DOI: https://doi.org/10.1134/S0020168510020020

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